Výsledky vyhledávání - "Levan Khulordava"

Synthetic control of the cis/trans geometry of [M(cyclam)(CCR)2]OTf complexes and photophysics of cis-[Cr(cyclam)(CCCF3)2]OTf and cis-[Rh(cyclam)(CCCF3)2]OTf

Autor: Chivin Sun, Colin D. McMillen, Levan Khulordava, Paul S. Wagenknecht, Parth U. Thakker

Publikováno v: Journal of Organometallic Chemistry. :107-112

During the synthesis of alkynyl complexes of the type [Cr(cyclam)(CCR)2]OTf from cis-[Cr(cyclam)(OTf)2]OTf, a cis to trans isomerization occurs that is dependent on the identity of the ether solvent. The isomerization occurs to a significant extent i

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d0255300d6b847001cdd244827a8abe9
https://doi.org/10.1016/j.jorganchem.2014.08.028

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Trifluoropropynyl as a surrogate for the cyano ligand and intense, room-temperature, metal-centered emission from its Rh(III) complex

Autor: David L. Grisenti, Levan Khulordava, Chivin Sun, Daniel J. Tobben, Seth Greenstein, Paul S. Wagenknecht, Andrew G. Kantor, Parth U. Thakker

Publikováno v: Inorganic chemistry. 51(20)

The trifluoropropynyl ligand -C≡CCF(3) was studied as a possible surrogate for the cyano ligand. Complexes of the type trans-[M(cyclam)(C≡CCF(3))(2)]OTf (where M = Cr(3+), Co(3+), and Rh(3+); OTf = trifluoromethanesulfonate) were prepared and the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08ea9e4f9880d08d205d4fb44d15be6b
https://pubmed.ncbi.nlm.nih.gov/23013542

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