Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Les J. Laughlin"'
Publikováno v:
Inorganic Chemistry. 46:939-948
The reactions of jade-green Tp*MoIVO(S2PR2) [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; R = Et, Pri, Ph] with propylene sulfide produce ochre-red Tp*MoVIOS{SP(S)R2}. The complexes have been characterized by microanalysis, mass spectrometry, cyc
Autor:
Charles G. Young, Andrew J. Millar, Edward R. T. Tiekink, Les J. Laughlin, Christian J. Doonan
Publikováno v:
Inorganica Chimica Acta. 337:393-406
Metathesis of Tp P r MoO 2 Cl (Tp P r = hydrotris(3-isopropylpyrazolyl)borate) with phenol/NEt 3 or thiol/NEt 3 mixtures results in the formation of air-stable, diamagnetic cis-dioxo-Mo(VI) complexes, Tp P r MoO 2 X (X = OC 6 H 4 sBu-2, OC 6 H 4 R-3
Autor:
Konstantinos D. Demadis, Dimitri Coucouvanis, Steven M. Malinak, Les J. Laughlin, Marni A. Tyson, Patrick E. Mosier
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 107:123-135
A functional model for nitrogenase is currently sought in our laboratory in reactivity studies using various single cubane clusters that possess the [MFe 3 S 4 ] n + core, (MMo, n = 3; MV, n = 2). These clusters are used as catalysts for the re
Publikováno v:
Inorganic Chemistry. 35:5368-5377
Reaction of MoIVO(S2PR2)2 with K{HB(Pripz)3} [HB(Pripz)3- = hydrotris(isopropylpyrazol-1-yl)borate] in refluxing toluene affords green L*MoIVO(S2PR2-S,S‘) complexes [L* = HB(3-Pripz)2(5-Pripz)- = hydrobis(3-isopropylpyrazol-1-yl)(5-isopropylpyrazol
Autor:
Les J. Laughlin, Dimitri Coucouvanis
Publikováno v:
Journal of the American Chemical Society. 117:3118-3125
Publikováno v:
Journal of the American Chemical Society. 114:9195-9197
Autor:
Charles G. Young, Les J. Laughlin
Publikováno v:
Inorganic chemistry. 35(4)
The oxo-Mo(IV) complexes LMoO(S(2)PR(2)-S,S') [L = hydrotris(3,5-dimethylpyrazol-1-yl)borate; R = Me, Et, Pr(i)(), Ph] were prepared by reacting MoO(S(2)PR(2))(2) and KL in refluxing toluene. The dioxo-Mo(VI) complexes cis-LMoO(2)(S(2)PR(2)-S) (R = P
Publikováno v:
Inorganic Chemistry. 35:3447-3448
This paper draws a contrast between the molecular and electronic structures of the oxo−thio−Mo(VI) complex LMoVIOS(S2PPr2-S) and the dithio−oxo−Mo(IV) complex LMoIVO(pyS2-N,S) [pyS2 = pyridyl-2-dithio; L = hydrotris(3,5-dimethylpyrazol-1-yl)b