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The enhanced mechanochemical reactivity of potassium hydroxide (KOH) in the presence of 18-crown-6 ether is supported by potassium complexation under milling and has been demonstrated in the Henry reaction and SNAr hydroxylation: in both cases, the d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::42a7c2450065b3a1d412a212db4ba3a6
https://doi.org/10.1039/d3nj00364g
https://doi.org/10.1039/d3nj00364g
Publikováno v:
Faraday discussions.
Inelastic collisions of the milling media in ball milling provide energy to the reaction mixture required for a chemical transformations. However, movement of the milling media results also in physical mixing of reactants, which too may enable a chem
Publikováno v:
Chemistry methods
Catalyzed reactions of organic substrates that operate continuously by extrusion techniques are rare. In this study, we developed a mechanochemical bromination of unactivated naphthalene (1) with 1, 3-dibromo-5, 5- dimethylhydantoin (DBDMH) catalyzed