Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Leonard C. Leitch"'
Publikováno v:
Canadian journal of research. 25(1)
The syntheses of 2-sulphanilamido-4-hydroxypyrimidine, 2-sulphanilamido-4,6-dihydroxypyrimidine, and several other sulphanilamidopyrimidines are described. An improved method for the preparation of sulphaguanidine is given.
Publikováno v:
Journal of Heterocyclic Chemistry. 28:411-416
Some alkyl-, alkenyl-, acyl- and nitrogen- derivatives of α-terthienyl 1 have been synthesized in an effort to expand the potential insecticidal activity profile of this compound. The introduction of substituents was carried out directly on the α-t
Publikováno v:
Tetrahedron. 44:2403-2412
A number of derivatives of α-terthienyl were prepared including a series of naturally occurring compounds. A description of the syntheses of some new compounds, including 5-iodo, 5,5'-diiodo, 5,5'-diformyl, 5.5'-di- tert butyl, 5,- tert -butyl, 5- t
Publikováno v:
Canadian Journal of Biochemistry. 58:986-995
Anesthetics bound to model membranes were observed directly by means of deuterium nuclear magnetic resonance (NMR). The specifically deuterated local anesthetics procaine and tetracaine were synthesized, and their partition coefficients (water:phosph
Publikováno v:
Canadian Journal of Research. :139-157
A number of attempts to prepare sulphanilylthiourea are described. The synthesis was accomplished by reacting acetylsulphanilylcyanamide with hydrogen sulphide under pressure and at elevated temperatures to form acetylsulphanilylthiourea, which was d
Publikováno v:
Canadian Journal of Research. :256-263
An improved method of preparing polymethylene, (CH2)n, by the decomposition of diazomethane is described. A new polymer, polyethylidene, (CH3∙CH)n, has been obtained from diazoethane by the same reaction. Diazomethane-d2 is reported for the first t
Autor:
Leonard C. Leitch
Publikováno v:
Canadian Journal of Chemistry. 33:400-404
The mechanism of the Nef reaction was investigated with nitroethane-1,1-d2. The isolation of 95 mole % ethanal-1-d in 70% yield renders a mechanism proposed by Mahler untenable, but supports others submitted by van Tamelen and Thiede and by Nametkin.
Publikováno v:
Canadian Journal of Research. :1-5
The synthesis of δ-3 (indolyl) -valeric acid, by a procedure analogous to that employed in the synthesis of its lower homologues, is described. It, as well as a bz-methyl derivative of β-3(indolyl)-propionic acid, which has also been synthesized, w
Autor:
J. Kaminski, John T. Arnason, C. W. Berg, Jørgen Lam, Peter Morand, Leonard C. Leitch, A. MacEachern, Bernard J. R. Philogène
Publikováno v:
Phytochemistry. 25:1609-1611
Naturally occurring and synthetic analogues and derivatives of polyacetylenes and thiophenes of the Asteraceae were investigated for their phototoxic effects on mosquito larvae, iodination, dimethylation in the 3′,4′-position or substitution of t
Autor:
C. W. Berg, R. G. Taylor, J. T. Arnason, Bernard J. R. Philogène, F. Duval, Leonard C. Leitch, Peter Morand, D. Champagne
Publikováno v:
Journal of economic entomology. 78(1)
New methods to synthesize alpha-terthienyl ( α-T ) on a large scale have permitted field and laboratory evaluation of this naturally occurring phototoxin from plants for blackfly and mosquito control. The acute toxicity of α-T to blackfly larvae (