Electroreduction of CO2/CO to C2 Products: Process Modeling, Downstream Separation, System Integration, and Economic Analysis

Autor: Andrew R. T. Morrison, Bert De Mot, Mahinder Ramdin, Paul A. Webley, Leo J. P. van den Broeke, Wiebren de Jong, J. P. Martin Trusler, Othonas A. Moultos, Ruud Kortlever, Thijs J. H. Vlugt, Tom Breugelmans, Penny Xiao

Publikováno v: Industrial & Engineering Chemistry Research
Industrial and Engineering Chemistry Research, 60(49)

Direct electrochemical reduction of CO2 to C2 products such as ethylene is more efficient in alkaline media, but it suffers from parasitic loss of reactants due to (bi)carbonate formation. A two-step process where the CO2 is first electrochemically r

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::202811e60ae46ac9d1a115dc1ae8b4f9
http://europepmc.org/articles/PMC8679093

Electro-osmotic Drag and Thermodynamic Properties of Water in Hydrated Nafion Membranes from Molecular Dynamics

Autor: Ahmadreza Rahbari, Remco Hartkamp, Othonas A. Moultos, Albert Bos, Leo J. P. van den Broeke, Mahinder Ramdin, David Dubbeldam, Alexey V. Lyulin, Thijs J. H. Vlugt

Publikováno v: Journal of Physical Chemistry C, 126(18), 8121-8133. American Chemical Society
Journal of Physical Chemistry C, 126(18). American Chemical Society
The Journal of Physical Chemistry C, 126(18)

One of the important parameters in water management of proton exchange membranes is the electro-osmotic drag (EOD) coefficient of water. The value of the EOD coefficient is difficult to justify, and available literature data on this for Nafion membra

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6d3d5a76aa9520e1ae755f18c1a3adc8
https://hdl.handle.net/11245.1/c1aaae98-6889-4918-ac76-f823a28a01bb

Solubilities and Transport Properties of CO2, Oxalic Acid, and Formic Acid in Mixed Solvents Composed of Deep Eutectic Solvents, Methanol, and Propylene Carbonate

Autor: Noura Dawass, Jilles Langeveld, Mahinder Ramdin, Elena Pérez-Gallent, Angel A. Villanueva, Erwin J. M. Giling, Jort Langerak, Leo J. P. van den Broeke, Thijs J. H. Vlugt, Othonas A. Moultos

Publikováno v: The Journal of Physical Chemistry Part B (Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter), 126(19)

Recently, deep eutectic solvents (DES) have been considered as possible electrolytes for the electrochemical reduction of CO2 to value-added products such as formic and oxalic acids. The applicability of pure DES as electrolytes is hindered by high v

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0451d53b29e399830f7796c4de9358be
http://resolver.tudelft.nl/uuid:7b8ec160-6cda-478c-97cd-cc6ae1745761

Liquid-Liquid Extraction of Formic Acid with 2-Methyltetrahydrofuran:Experiments, Process Modeling, and Economics

Autor: Thijs J. H. Vlugt, Marco Huotari, Leo J. P. van den Broeke, Antero Laitinen, Mahinder Ramdin, Olli Jauhiainen, Wiebren de Jong, Vyomesh M. Parsana

Publikováno v: Laitinen, A T, Parsana, V M, Jauhiainen, O, Huotari, M, Van Den Broeke, L J P, De Jong, W, Vlugt, T J H & Ramdin, M 2021, ' Liquid-Liquid Extraction of Formic Acid with 2-Methyltetrahydrofuran : Experiments, Process Modeling, and Economics ', Industrial and Engineering Chemistry Research, vol. 60, no. 15, pp. 5588–5599 . https://doi.org/10.1021/acs.iecr.1c00159
Industrial & Engineering Chemistry Research
Industrial and Engineering Chemistry Research, 60(15)

Formic acid (FA) is an interesting hydrogen (H2) and carbon monoxide (CO) carrier that can be produced by the electrochemical reduction of carbon dioxide (CO2) using renewable energy. The separation of FA from water is challenging due to the strong (

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb6325e95bf036e443b9aa8f7d18a3cb
https://cris.vtt.fi/en/publications/68b0b383-a0f6-41d2-8ee1-222d9bf1ab89

CO2 solubility in small carboxylic acids: Monte Carlo simulations and PC-SAFT modeling

Autor: Thijs J. H. Vlugt, Mahinder Ramdin, Seyed Hossein Jamali, Leo J. P. van den Broeke, Wim Buijs

Publikováno v: Fluid Phase Equilibria. 458:1-8

Carbon dioxide (CO2) can electrochemically be converted to a range of products including formic acid (HCOOH) and acetic acid (CH3COOH). The yield of the products in an electrolysis cell depends on the solubility of CO2 in the (aqueous) mixture. In ab

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e7c88a188abd591746883c93352a5475
https://doi.org/10.1016/j.fluid.2017.11.001