Enhancement of CO2Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality

Autor: Bolotov, VA, Kovalenko, KA, Samsonenko, DG, Han, X, Zhang, X, Smith, GL, McCormick, LJ, Teat, SJ, Yang, S, Lennox, MJ, Henley, A, Besley, E, Fedin, VP, Dybtsev, DN, Schröder, M

Publikováno v: Bolotov, VA; Kovalenko, KA; Samsonenko, DG; Han, X; Zhang, X; Smith, GL; et al.(2018). Enhancement of CO2Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality. Inorganic Chemistry, 57(9), 5074-5082. doi: 10.1021/acs.inorgchem.8b00138. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/2f60x4h6

© 2018 American Chemical Society. The complex [Zn2(tdc)2dabco] (H2tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in carbon dioxide (CO2) uptake and CO2/dinitrogen (N2) selectivity compared to the n

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http://www.escholarship.org/uc/item/2f60x4h6

Enhancement of CO 2 Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality.

Autor: Bolotov VA; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation., Kovalenko KA; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.; Novosibirsk State University , 2 Pirogova Street , Novosibirsk 630090 , Russian Federation., Samsonenko DG; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.; Novosibirsk State University , 2 Pirogova Street , Novosibirsk 630090 , Russian Federation., Han X; School of Chemistry , University of Manchester , Manchester M13 9PL , U.K., Zhang X; School of Chemistry , University of Manchester , Manchester M13 9PL , U.K., Smith GL; School of Chemistry , University of Manchester , Manchester M13 9PL , U.K., McCormick LJ; Advanced Light Source , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States., Teat SJ; Advanced Light Source , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States., Yang S; School of Chemistry , University of Manchester , Manchester M13 9PL , U.K., Lennox MJ; Centre for Advanced Separations Engineering, Department of Chemical Engineering , University of Bath , Bath BA2 7AY , U.K.; School of Chemistry , University of Nottingham , Nottingham NG7 2RD , U.K., Henley A; School of Chemistry , University of Nottingham , Nottingham NG7 2RD , U.K., Besley E; School of Chemistry , University of Nottingham , Nottingham NG7 2RD , U.K., Fedin VP; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.; Novosibirsk State University , 2 Pirogova Street , Novosibirsk 630090 , Russian Federation., Dybtsev DN; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.; Novosibirsk State University , 2 Pirogova Street , Novosibirsk 630090 , Russian Federation., Schröder M; Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.; School of Chemistry , University of Manchester , Manchester M13 9PL , U.K.

Publikováno v: Inorganic chemistry [Inorg Chem] 2018 May 07; Vol. 57 (9), pp. 5074-5082. Date of Electronic Publication: 2018 Apr 23.

Ultra-large supramolecular coordination cages composed of endohedral Archimedean and Platonic bodies.

Autor: Byrne K; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland.; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland., Zubair M; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland.; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland., Zhu N; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland.; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland.; Institute of Molecular Functional Materials &Department of Chemistry, Hong Kong Baptist University, 224 Waterloo Road, Hong Kong, Hong Kong., Zhou XP; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland.; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland., Fox DS; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland.; School of Physics University of Dublin, Trinity College, Dublin 2, Ireland., Zhang H; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland.; School of Physics University of Dublin, Trinity College, Dublin 2, Ireland., Twamley B; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland., Lennox MJ; Centre for Advanced Separations Engineering, Department of Chemical Engineering, University of Bath, Bath BA2 7AY, UK., Düren T; Centre for Advanced Separations Engineering, Department of Chemical Engineering, University of Bath, Bath BA2 7AY, UK., Schmitt W; School of Chemistry, University of Dublin, Trinity College, Dublin 2, Ireland.; CRANN Nanotechnology Institute &AMBER, Centre University of Dublin, Trinity College, Dublin 2, Ireland.

Publikováno v: Nature communications [Nat Commun] 2017 May 09; Vol. 8, pp. 15268. Date of Electronic Publication: 2017 May 09.

Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal-Organic Framework.

Autor: Benson O; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., da Silva I; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, U.K., Argent SP; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Cabot R; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Savage M; School of Chemistry, University of Manchester , Manchester, M13 9PL, U.K., Godfrey HG; School of Chemistry, University of Manchester , Manchester, M13 9PL, U.K., Yan Y; School of Chemistry, University of Manchester , Manchester, M13 9PL, U.K., Parker SF; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, U.K., Manuel P; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, U.K., Lennox MJ; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Mitra T; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K.; Department of Chemistry, University of Liverpool , Liverpool, L69 7ZD, U.K., Easun TL; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K.; School of Chemistry, Cardiff University , Cardiff, CF10 3XQ, U.K., Lewis W; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Blake AJ; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Besley E; School of Chemistry, University of Nottingham , Nottingham, NG7 2RD, U.K., Yang S; School of Chemistry, University of Manchester , Manchester, M13 9PL, U.K., Schröder M; School of Chemistry, University of Manchester , Manchester, M13 9PL, U.K.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2016 Nov 16; Vol. 138 (45), pp. 14828-14831. Date of Electronic Publication: 2016 Nov 01.

Hetero-epitaxial approach by using labile coordination sites to prepare catenated metal-organic frameworks with high surface areas.

Autor: Zhu N; School of Chemistry & CRANN, University of Dublin, Trinity College, Dublin 2 (Ireland)., Lennox MJ, Tobin G, Goodman L, Düren T, Schmitt W

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2014 Mar 24; Vol. 20 (13), pp. 3595-9. Date of Electronic Publication: 2014 Feb 24.