Synthesis and Structural Characterization of a Non-Heme Iron Hyponitrite Complex.

Autor: Lengel MO; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109-1055., Dong HT; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109-1055., Lehnert N; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109-1055.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Dec 02; Vol. 63 (49), pp. e202409700. Date of Electronic Publication: 2024 Nov 05.

What Is the Right Level of Activation of a High-Spin {FeNO} ⁷ Complex to Enable Direct N-N Coupling? Mechanistic Insight into Flavodiiron NO Reductases.

Autor: Dong HT, Camarena S, Sil D; Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States., Lengel MO, Zhao J; Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, Illinois 60439, United States., Hu MY; Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, Illinois 60439, United States., Alp EE; Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, Illinois 60439, United States., Krebs C; Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.; Department of Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States., Lehnert N

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2022 Sep 14; Vol. 144 (36), pp. 16395-16409. Date of Electronic Publication: 2022 Aug 30.

Distortion of the [FeNO] 2 Core in Flavodiiron Nitric Oxide Reductase Models Inhibits N-N Bond Formation and Promotes Formation of Unusual Dinitrosyl Iron Complexes: Implications for Catalysis and Reactivity.

Autor: White CJ; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States., Lengel MO; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States., Bracken AJ; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States., Kampf JW; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States., Speelman AL; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States., Alp EE; Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States., Hu MY; Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States., Zhao J; Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States., Lehnert N; Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2022 Mar 09; Vol. 144 (9), pp. 3804-3820. Date of Electronic Publication: 2022 Feb 25.