Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Autor: Leggett, CJ, Parker, BF, Teat, SJ, Zhang, Z, Dau, PD, Lukens, WW, Peterson, SM, Cardenas, AJP, Warner, MG, Gibson, JK, Arnold, J, Rao, L

Publikováno v: Chemical science, vol 7, iss 4
Leggett, CJ; Parker, BF; Teat, SJ; Zhang, Z; Dau, PD; Lukens, WW; et al.(2016). Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. Chemical Science, 7(4), 2775-2786. doi: 10.1039/c5sc03958d. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/2p03j1ms

A non-oxido V(v) complex with glutaroimide-dioxime (H3L), a ligand for recovering uranium from seawater, was synthesized from aqueous solution as Na[V(L)2]·2H2O, and the structure determined by X-ray diffraction. It is the first non-oxido V(v) compl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::226d1f13c9b3ff6232f9f41aecad1c9b
https://escholarship.org/uc/item/2p03j1ms

Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater.

Autor: Ivanov AS; Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Leggett CJ; Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.; U. S. Nuclear Regulatory Commission, Rockville, MD, 20852, USA., Parker BF; Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.; University of California-Berkeley, Berkeley, CA, 94720, USA., Zhang Z; Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA., Arnold J; Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.; University of California-Berkeley, Berkeley, CA, 94720, USA., Dai S; Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Abney CW; Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. abneycw@ornl.gov., Bryantsev VS; Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. bryantsevv@ornl.gov., Rao L; Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA. lrao@lbl.gov.

Publikováno v: Nature communications [Nat Commun] 2017 Nov 16; Vol. 8 (1), pp. 1560. Date of Electronic Publication: 2017 Nov 16.

Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution.

Autor: Leggett CJ; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov., Parker BF; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov.; Department of Chemistry , University of California - Berkeley , Berkeley , CA 94720 , USA., Teat SJ; Advanced Light Source , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: SJTeat@lbl.gov., Zhang Z; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov., Dau PD; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov., Lukens WW; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov., Peterson SM; National Security Directorate , Pacific Northwest National Laboratory , 902 Battelle Blvd. , Richland , WA 99352 , USA., Cardenas AJP; Fundamental and Computational Sciences Directorate , Pacific Northwest National Laboratory , 902 Battelle Blvd. , Richland , WA 99352 , USA., Warner MG; National Security Directorate , Pacific Northwest National Laboratory , 902 Battelle Blvd. , Richland , WA 99352 , USA., Gibson JK; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov., Arnold J; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov.; Department of Chemistry , University of California - Berkeley , Berkeley , CA 94720 , USA., Rao L; Chemical Sciences Division , Lawrence Berkeley National Laboratory , 1 Cyclotron Road , Berkeley , CA 94720 , USA . Email: LRao@lbl.gov.

Publikováno v: Chemical science [Chem Sci] 2016 Apr 01; Vol. 7 (4), pp. 2775-2786. Date of Electronic Publication: 2016 Jan 14.