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pro vyhledávání: '"Lee Galyer"'
The photoelectron spectra of WMe6, ReMe6, TaMe5, ReOMe5, and ReO(CH2SiMe3)4 are presented. For the hexamethyls an ionization energy ordering of 3tu, < 2a1G < 2eg is proposed.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::53f78003c497d03d8495ab30b50aa23b
https://ora.ox.ac.uk/objects/uuid:57610362-f41e-4103-9ec4-cc3c8d1b7b5a
https://ora.ox.ac.uk/objects/uuid:57610362-f41e-4103-9ec4-cc3c8d1b7b5a
Autor:
A. Lee Galyer, Robert W. Hay
Publikováno v:
Transition Metal Chemistry. 22:97-100
Copper(II) and nickel(II) complexes of 2-(benzylthio)ethylamine have been isolated and characterized by elemental analysis, i.r., solid state electronic spectra and magnetic susceptibility measurements.
Publikováno v:
Chemischer Informationsdienst. 9
Publikováno v:
Angewandte Chemie. 88:692-693
Publikováno v:
Journal of Organometallic Chemistry. 85:C37-C38
A new synthesis of hexamethyltungsten involves the reaction of WCl 6 and AlMe 3 , while interaction of AlMe 3 and ReOMe 4 gives ReMe 6 ; a dioxorhenium(VII) methyl, ReO 2 Me 3 , is reported.
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :497
The He I and He II photoelectron spectra of an authentic sample of hexamethyltungsten and of pentamethyltantalum are consistent with octahedral symmetry for the former and D3h symmetry for the latter; the metal-to-carbon bonding appears to be mainly
Publikováno v:
Journal of Organometallic Chemistry. 97:C65
Publikováno v:
Angewandte Chemie International Edition in English. 15:609-609
Autor:
A. Lee Galyer, Geoffrey Wilkinson
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2235
The interaction of tungsten hexachloride and trimethylaluminium in a hydrocarbon solvent followed by removal of chlorodimethylaluminium with an amine allows the synthesis of multigram quantities of hexamethyltungsten.Interaction of WMe6 with an exces