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pro vyhledávání: '"Lawrence T. C. Law"'
Autor:
Lin-Hong Weng, Wai Him Kwok, Wing-Por Leung, Zhongyuan Zhou, Lawrence T. C. Law, Thomas C. W. Mak
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :4301-4306
A series of heavier main Group 14 metal dialkyls MR2 [R = R1 = CPh(SiMe3)(C5H4N-2), M = Ge 1 or Sn 2; R = R2 = CH(SiMe3)(C9H6N-8), M = Sn 3 or Pb 4] has been synthesized by the reaction of 2 equivalents of the appropriate lithium reagents LiR(tmen) (
Publikováno v:
Chem. Commun.. :505-506
The tin(II) alkyl (R[graphic omitted] 1 [RN= CH(SiMe3)C9H6N-8] reacts with elemental chalcogens in thf to afford thermally stable dimeric dialkylstannane-thione [RN(R[graphic omitted](µ-S)]22 and monomeric dialkylstannane-selone and -tellurone [(R[g