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pro vyhledávání: '"Lauren N. Mendelsohn"'
A cobalt-catalyzed reductive hydroformylation of terminal and 1,1-disubstituted alkenes is described. One-carbon homologated alcohols were synthe-sized directly from CO and H2, affording anti-Markovnikov products (34–87% yield) with exclu-sive regi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f417d89b7243a3ba980787910bf8095
https://doi.org/10.26434/chemrxiv-2022-ftnzw
https://doi.org/10.26434/chemrxiv-2022-ftnzw
Autor:
Lei Tian, Lauren N. Mendelsohn, Connor S. MacNeil, Paul J. Chirik, Gregory D. Scholes, Yoonsu Park
Publikováno v:
ACS Catalysis. 11:1351-1360
The catalytic hydrogenation activity of the readily prepared, coordinatively saturated cobalt(I) precatalyst, (R,R)-(iPrDuPhos)Co(CO)2H ((R,R)-iPrDuPhos = (+)-1,2-bis[(2R,5R)-2,5-diisopropylphospho...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::efeb6ab5f9252d4c21255dd4cb15290b
https://doi.org/10.1021/acscatal.0c05136
https://doi.org/10.1021/acscatal.0c05136
Autor:
Lauren N. Mendelsohn, Ljiljana Pavlovic, Hongyu Zhong, Max R. Friedfeld, Michael Shevlin, Kathrin H. Hopmann, Paul J. Chirik
The mechanism of the asymmetric hydrogenation of prochiral enamides by well-defined, neutral bis(phosphine) cobalt(0) and cobalt(II) precatalysts has been explored using(R,R)-iPrDuPhos ((R,R)-iPrDuPhos = (+)-1,2-bis[(2R,5R)-2,5-diisopropylphospholano
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::45c0dcc5546b67b1ffa5871d3729d5d8
https://hdl.handle.net/10037/28477
https://hdl.handle.net/10037/28477
Publikováno v:
Angewandte Chemie (International ed. in English). 59(23)
Intermediates relevant to cobalt-catalyzed alkene hydroformylation have been isolated and evaluated in fundamental organometallic transformations relevant to aldehyde formation. The 18-electron (R,R)-(iPr DuPhos)Co(CO)2 H has been structurally charac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::64e6c88cfa9e7d9a35c6bb58d2a922b6
https://pubmed.ncbi.nlm.nih.gov/32182395
https://pubmed.ncbi.nlm.nih.gov/32182395
Autor:
MacNeil, Connor S.1 (AUTHOR), Mendelsohn, Lauren N.1 (AUTHOR), Zhong, Hongyu1 (AUTHOR), Pabst, Tyler P.1 (AUTHOR), Chirik, Paul J.1 (AUTHOR) pchirik@princeton.edu
Publikováno v:
Angewandte Chemie. 6/2/2020, Vol. 132 Issue 23, p8997-9001. 5p.