Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Laura Puig-Urrea"'
Publikováno v:
Inorganic Chemistry. 60:4162-4170
Neutral arenes such as benzene have never been considered suitable ligands for electropositive actinide cations, yet we find that even simple UIII UX3 aryloxide complexes such as U(ODipp)3 bind and reduce arenes spontaneously at room temperature, for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e744c5c76f84752236b7d047780b000f
https://doi.org/10.1021/acs.inorgchem.1c00327
https://doi.org/10.1021/acs.inorgchem.1c00327
Autor:
Polly L. Arnold, Jordann A. L. Wells, Faye L. Cruickshank, Laura Puig-Urrea, Dan Yuan, Rowan D. Young
Publikováno v:
Arnold, P L, Puig-urrea, L, Wells, J A L, Yuan, D, Cruickshank, F & Young, R D 2019, ' Applications of boroxide ligands in supporting small molecule activation by U(iii) and U(iv) complexes ', Dalton Transactions . https://doi.org/10.1039/C8DT05051A
The boroxide ligand [OBAr2]- (Ar = Mes, Trip) is shown to be able to support both UIII and UIV centres for the first time. The synthesis and structures of homoleptic and heteroleptic UIII and UIV complexes are reported. The UX3 complex with larger su
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f3c59ea9a0259d01ed7e71a74e366563
https://pubmed.ncbi.nlm.nih.gov/30924481
https://pubmed.ncbi.nlm.nih.gov/30924481