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Publikováno v:
Journal of the American Chemical Society. 139:14620-14637
Herein we delineate an unusual one-dimensional coordination polymer (CP), 3, prepared from S = 1/2 Co(TPP), 1 (TPP = 5,10,15,20-tetraphenylporphyrin dianion), and S = 1/2 4-(4′-pyridyl)-1,2,3,5-dithiadiazolyl (py-DTDA) radical, 2. The atypically lo
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 2751-2755 (2014)
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry
The diastereoselective oxazoline-directed lithiation of calix[4]arenes is reported with diastereoselective ratios of greater than 100:1 in some instances. Notably, it has been found that the opposite diastereomer can be accessed via this approach mer
Publikováno v:
Acta Crystallographica Section A Foundations and Advances. 70:C1241-C1241
The 1,2,3,5-dithiadiazolyl radicals (R-CNSSN) are of considerable interest due to their potential as building blocks for materials with interesting magnetic or conducting properties. The behaviour of these neutral radicals as ligands has also been in