Zobrazeno 1 - 10 of 10 pro vyhledávání: '"Laura C, Stevenson"'
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New Titanium Borylimido Compounds: Synthesis, Structure, and Bonding
Autor: Benjamin A, Clough, Simona, Mellino, Andrey V, Protchenko, Martin, Slusarczyk, Laura C, Stevenson, Matthew P, Blake, Bowen, Xie, Eric, Clot, Philip, Mountford
Publikováno v: Inorganic chemistry. 56(17)
We report a combined experimental and computational study of the synthesis and electronic structure of titanium borylimido compounds. Three new synthetic routes to this hitherto almost unknown class of Group 4 imide are presented. The double-deproton
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::4569d865f66226a8b5c8f979815a2427
https://pubmed.ncbi.nlm.nih.gov/28836774
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5
Reactions of Titanium Hydrazides with Silanes and Boranes: N-N Bond Cleavage and N Atom Functionalization
Autor: Laura C. Stevenson, Simona Mellino, Philip Mountford, Eric Clot
Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2015, 137, pp.10140-10143. ⟨10.1021/jacs.5b06627⟩
International audience; Reaction of Ti(N2iPrN)(NNPh2)(py) with Ph(R)SiH2 (R = H, Ph) or 9-BBN gave reductive cleavage of the Nα–Nβ bond and formation of new silyl- or boryl-amido ligands. The corresponding reactions of Cp*Ti{MeC(NiPr)2}(NNR2) (R
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::200bee8a40c5b5ace3edf02a64082227
https://pubmed.ncbi.nlm.nih.gov/26226513
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