Sustainable oxidative cleavage of catechols for the synthesis of muconic acid and muconolactones including lignin upgrading

Autor: Christophe Darcel, Frédéric Caijo, Florentin Coupé, Paul T. Anastas, Vincent Escande, Laurène Petitjean

Publikováno v: Green Chemistry
Green Chemistry, 2020, 22 (18), pp.6204-6211. ⟨10.1039/d0gc02157a⟩
Green Chemistry, Royal Society of Chemistry, 2020, 22 (18), pp.6204-6211. ⟨10.1039/d0gc02157a⟩

International audience; Muconic acid and muconolactones are attracting high interest as platform molecules for the synthesis of a variety of compounds, especially in the domain of materials. Although several technologies have been described for their

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ae2f9facd417f8ca243eaaf24684b4d
https://doi.org/10.1039/d0gc02157a

Exploration of a Novel, Enamine-Solid-Base Catalyzed Aldol Condensation with C-Glycosidic Pyranoses and Furanoses

Autor: Julien Hitce, Philip Coish, Yanna Balland, Tamara M. de Winter, Arwen Evenstar Neski, Julie B. Zimmerman, Laurène Petitjean, Magali Moreau, Paul T. Anastas, Hanno C. Erythropel

Publikováno v: ACS Sustainable Chemistry & Engineering. 6:11196-11199

A variety of unprotected C-glycosidic ketones were employed in a novel enamine-solid-base catalyzed (ESBC) aldol condensation to expand the scope and scalability of a previously reported reaction. The starting ketones were obtained from unprotected p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9b8922a744f5ac54bbc7cf38b41eb285
https://doi.org/10.1021/acssuschemeng.8b02535

The Green ChemisTREE: 20 years after taking root with the 12 principles

Autor: Fjodor Melnikov, Nina Z. Janković, Qingshi Tu, Tamara M. de Winter, Wenbo Shi, Julie B. Zimmerman, Karolina E. Mellor, A.W. Lounsbury, Desiree L. Plata, Lauren N. Pincus, Chun Ho Lam, Laurène Petitjean, Philip Coish, Hanno C. Erythropel, Paul T. Anastas, Mark M. Falinski

Publikováno v: Green Chemistry. 20:1929-1961

The field of Green Chemistry has seen many scientific discoveries and inventions during the 20 years since the 12 Principles were first published. Inspired by tree diagrams that illustrate diversity of products stemming from raw materials, we present

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a45aff562739934a4bbdd04731a11641
https://doi.org/10.1039/c8gc00482j

Development of 3,5-Di-tert-butylphenol as a Model Substrate for Biomimetic Aerobic Copper Catalysis

Autor: Laurène Petitjean, Xavier Ottenwaelder, Jean-Philip Lumb, Ohhyeon Kwon, Kenneth Virgel N. Esguerra, Yalun Xu, Michael Glazerman

Publikováno v: Synlett. 28:1548-1553

We develop 3,5-di- tert­ butylphenol as a strategic substrate for the evaluation of biomimetic Cu 2 –O 2 complexes intended to mimic the activity of tyrosinase. We describe a practical and scalable synthesis and validate its use in an aerobic orth

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0fd99d7a9ec8687829d6bdb10a9ece6b
https://doi.org/10.1055/s-0036-1588761

Highly selective hydrogenation and hydrogenolysis using a copper-doped porous metal oxide catalyst

Autor: Laurène Petitjean, Raphael Gagne, Dequan Xiao, Evan S. Beach, Paul T. Anastas

Publikováno v: Green Chemistry. 18:150-156

A copper-doped porous metal oxide catalyst in combination with hydrogen shows selective and quantitative hydrogenolysis of benzyl ketones and aldehydes, and hydrogenation of alkenes. The approach provides an alternative to noble-metal catalysed reduc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5bc3a40835fa04f1104c8e3d70395c11
https://doi.org/10.1039/c5gc01464f