Accumulation and distribution of higher hydrocarbons in the pores of a cobalt catalyst during low-temperature Fischer–Tropsch fixed-bed synthesis

Autor: Lasse Schurm, Andreas Jess, Christoph Kern

Publikováno v: Catalysis Science & Technology. 11:6143-6154

During low-temperature Fischer–Tropsch synthesis (FTS), the catalyst pores are filled with liquid hydrocarbons. In a fixed-bed reactor, axial concentration gradients are present in the gas phase (CO, H2, evaporated hydrocarbons (HCs)). This leads t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d57d361e92403cda4e9928b7257ca849
https://doi.org/10.1039/d1cy01305j

Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins

Autor: Sébastien Tilloy, Jens M. Dreimann, D. Lange, Kai U. Künnemann, Thomas Seidensticker, Lasse Schurm, Dieter Vogt, Eric Monflier

Publikováno v: Green Chemistry
Green Chemistry, 2020, 22 (12), pp.3809-3819. ⟨10.1039/D0GC00820F⟩
Green Chemistry, Royal Society of Chemistry, 2020, 22 (12), pp.3809-3819. ⟨10.1039/D0GC00820F⟩

For the first time, randomly methylated β-cyclodextrin was applied as the mass transfer agent in a continuous process. Considering the example of the Rh-catalyzed hydroformylation of 1-decene, process development was shown, where cyclodextrin was us

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e750ae6be58ae451093712eca0dd19ac
https://hal.science/hal-02881844