Zobrazeno 1 - 10
of 194
pro vyhledávání: '"Lars Wesemann"'
Autor:
Maximilian Auer, Janina Bolten, Klaus Eichele, Hartmut Schubert, Christian P. Sindlinger, Lars Wesemann
Publikováno v:
Chemical Science. 14:514-524
Tetrylidinium–iridium cations [ArE = IrHL3]+ (E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal–ligand Lewis acid enabling 1,2-addition of NH3, N2H4, H2O, HCl and H2.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e3356233ffb9f7d3283f8b77b255d768
https://doi.org/10.1039/d2sc05620h
https://doi.org/10.1039/d2sc05620h
Publikováno v:
Journal of the American Chemical Society.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ac394fd6ef93512d02b27ede36cce714
https://doi.org/10.1021/jacs.3c03744
https://doi.org/10.1021/jacs.3c03744
Publikováno v:
Angewandte Chemie International Edition.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::17ee3c461ff08dbac85d2e82feb1cc45
https://doi.org/10.1002/anie.202304200
https://doi.org/10.1002/anie.202304200
Autor:
Ralf H. Kern, Meike Schneider, Klaus Eichele, Hartmut Schubert, Holger F. Bettinger, Lars Wesemann
Publikováno v:
Angewandte Chemie. 135
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1c1f6653b4a523978c6e8dbfaa3e6eb9
https://doi.org/10.1002/ange.202301593
https://doi.org/10.1002/ange.202301593
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The reaction of the intramolecular germylene‐phosphine Lewis pair (o‐PPh2)C6H4GeAr* (1) with Group 15 element trichlorides ECl3 (E=P, As, Sb) was investigated. After oxidative addition, the resulting compounds (o‐PPh2)C6H4(Ar*)Ge(Cl)ECl2 (2: E=
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f93b948274f74a60324acfc4d2fbf1e7
https://doi.org/10.1002/chem.202102320
https://doi.org/10.1002/chem.202102320
Autor:
Max Widemann, Christian P. Sindlinger, Lars Wesemann, Steffen Klenner, Hartmut Schubert, Rainer Pöttgen, Klaus Eichele
Publikováno v:
Angewandte Chemie International Edition. 60:5882-5889
Tetrylidynes [(Me3 P)2 (Ph3 P)Rh≡SnAr*] (10) and [(Me3 P)2 (Ph3 P)Rh≡PbAr*] (11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3 P)2 RhH2 SnAr*] (3) and [(Ph3 P)2 RhH2 PbAr*] (7) (Ar*=2,6-Trip2 C6 H3 , Trip=2,4,6-triisopro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b77df3a9a4120a03af2642bca62e9e36
https://doi.org/10.1002/anie.202015725
https://doi.org/10.1002/anie.202015725
Autor:
Christian P. Sindlinger, Lars Wesemann, Klaus Eichele, Steffen Klenner, Rainer Pöttgen, Hartmut Schubert, Max Widemann
Publikováno v:
Angewandte Chemie. 133:5946-5953
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::07dd92344376eeabe11304e1c6c1f9e3
https://doi.org/10.1002/ange.202015725
https://doi.org/10.1002/ange.202015725
Publikováno v:
Dalton Transactions. 50:11814-11820
The ruthenium carbene pincer complex 2 was synthesized treating the benzo annulated cycloheptatriene bisphosphine 1 with RuCl3. Addition of three equivalents of hydrogen to the carbocyclic carbene complex 2 was achieved in reaction of 2 with hydrogen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::417e143c72bf6ee25d8e59365418cdeb
https://doi.org/10.1039/d1dt02266k
https://doi.org/10.1039/d1dt02266k
Autor:
Max Widemann, Frederik S. W. Aicher, Martin Bonath, Klaus Eichele, Cäcilia Maichle‐Mössmer, Hartmut Schubert, Peter Sirsch, Reiner Anwander, Lars Wesemann
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(45)
Following the alkane-elimination route, the reaction between tetravalent aryl tintrihydride Ar*SnH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9ad8804f4d21c1f5ffff7ed5354c229e
https://pubmed.ncbi.nlm.nih.gov/35620817
https://pubmed.ncbi.nlm.nih.gov/35620817
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(15)
TbbEH3 of germanium and tin were synthesized, and their deprotonation, hydride abstraction and hydrogen elimination were studied.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f85b34ba9c83088c09bcd3867bd2fd7
https://pubmed.ncbi.nlm.nih.gov/35348165
https://pubmed.ncbi.nlm.nih.gov/35348165