Water and 2,2,6,6-tetramethylpiperidine: an odd couple make a solid match

Autor: Larry R. Falvello

Publikováno v: IUCrJ, Vol 9, Iss 3, Pp 331-332 (2022)

Externí odkaz: https://doaj.org/article/fa5679ef22ff478585545070574ab02c

Synthesis of 1,2-diaminotruxinic d-cyclobutanes by BF3-controlled [2 + 2]-photocycloaddition of 5(4H)-oxazolones and stereoselective expansion of d-cyclobutanes to give highly substituted pyrrolidine-2,5-dicarboxylates

Autor: Sonia Sierra, Rosa López, Enrique Gómez-Bengoa, Larry R. Falvello, Esteban P. Urriolabeitia

The irradiation of (Z)-4-arylidene-5(4H)-oxazolones 1a–1u with blue light (465 nm) in the presence of the photosensitizer [Ru(bpy)3](BF4)2 (2.5 mol%) and the Lewis acid BF3·OEt2 (2 equiv.) in deoxygenated methanol at room temperature affords the c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4ea15a044bae30cabe43a15ac313dad1
http://zaguan.unizar.es/record/126310

Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N-O Bond Cleavage Reactions

Autor: M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Ana M. Guerra, Miguel A. Ruiz, Larry R. Falvello

Publikováno v: Scopus

The novel nitrosyl-bridged complex [W2Cp2(μ-PtBu2)(μ-κ:η-NO)(CO)(NO)](BAr4) [Ar = 3,5-C6H3(CF3)2] was prepared in a multistep procedure starting from the hydride [W2Cp2(μ-H)(μ-PtBu2)(CO)4] and involving the new complexes [W2Cp2(μ-PtBu2)(CO)4](

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4bb14229ba4488fb4f0f13490907fa8
https://pubmed.ncbi.nlm.nih.gov/36106823

Temperature-dependent dimerization of TCNQ anion-radical in [Ni(bpy)3]2(TCNQ–TCNQ)(TCNQ)2·6H2O: Single-crystal structure, magnetic and quantum chemical study

Autor: Slavomíra Šterbinská, Mariia Holub, Michal Hegedüs, Ján Titiš, Erik Čižmár, Larry R. Falvello, Juraj Černák

Publikováno v: Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname
Digital.CSIC. Repositorio Institucional del CSIC

The crystal structure of [Ni(bpy)3]2(TCNQ–TCNQ)(TCNQ)2·6H2O (1) was studied by X-ray single-crystal structure analysis at 145 K and 100 K. The crystal structures of 1 at these two temperatures are essentially the same as the crystal structure stud

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b304a1b467cd0b2430fb9f8ec82b06d3
http://hdl.handle.net/10261/280738

Tetra-n-butyl­ammonium orotate monohydrate: knowledge-based comparison of the results of accurate and lower-resolution analyses and a non-routine disorder refinement

Autor: Larry R. Falvello, Mohsen Graia, Pablo Guerra, Zeineb Basdouri, Irene Ara, Milagros Tomás

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications
Digital.CSIC. Repositorio Institucional del CSIC
instname
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 11, Pp 1632-1637 (2019)

The title hydrated mol­ecular salt (systematic name: tetra-n-butyl­ammonium 2,6-dioxo-1,2,3,6-tetra­hydro­pyrimidine-4-carboxyl­ate monohydrate), C16H36N+·C5H3N2O4 −·H2O, crystallizes with N—H⋯O and O—H⋯O hydrogen-bonded double-stran

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::152751b0452662429f5f9a92d71624b4
http://europepmc.org/articles/PMC6829738