Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Laith R. Almazahreh"'
Publikováno v:
Inorganics, Vol 7, Iss 4, p 50 (2019)
The electrochemical reduction of the complex [Fe2(CO)6{µ-(SCH2)2GeMe2}] (1) under N2 and CO is reported applying cyclic voltammetry. Reduction of complex 1 in CO saturated solutions prevents the possible release of CO from the dianion 12−, while t
Externí odkaz:
https://doaj.org/article/cff39d90e0ce46228efcd7d34900614b
Autor:
Wolfgang Weigand, Laith R. Almazahreh, Hassan Abul-Futouh, Helmar Görls, Sven T. Stripp, Sara J. Abaalkhail
The synthesis and characterization of Fe2(CO)5(L){μ-(SCH2)2}SnMe2 (L = PPh3 (2) and P(OMe)3 (3) derived from the parent hexacarbonyl complex Fe2(CO)6{μ-(SCH2)2}SnMe2 (1) is reported. Whereas 1 exhibits a unique planar structure, X-ray crystallograp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e69c657c32ef2fb6dfa7f850c137308
Autor:
Manfred Rudolph, Helmar Görls, Federica Arrigoni, Luca Bertini, Philippe Schollhammer, Hassan Abul-Futouh, Wolfgang Weigand, Laith R. Almazahreh, Giuseppe Zampella, Catherine Elleouet, Luca De Gioia, Mohammad El-khateeb
Publikováno v:
ACS Catalysis
ACS Catalysis, American Chemical Society, 2021, pp.7080-7098. ⟨10.1021/acscatal.0c05563⟩
ACS Catalysis, American Chemical Society, 2021, pp.7080-7098. ⟨10.1021/acscatal.0c05563⟩
International audience; The synthesis, characterization, and protonation of [Fe2(CO)6{(μ-SCH2)2(Et)P═O}] (1) using the moderately strong acid CF3CO2H (pKaMeCN = 12.7) are reported. Digital simulations of the cyclic voltammetry of 1 in the presence
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::edd9a81f32c419f434bdbd5ec565df8d
https://hal.univ-brest.fr/hal-03251619
https://hal.univ-brest.fr/hal-03251619
Autor:
Ralf Trautwein, Wolfgang Weigand, Laith R. Almazahreh, Helmar Görls, Wolfgang Imhof, Hassan Abul-Futouh
Publikováno v:
New Journal of Chemistry. 43:12580-12593
Three diiron hexacarbonyl complexes containing dithiolato (5), diselenolato (6), and selenolato-thiolato ligands (7), respectively, have been prepared as [FeFe]-hydrogenase mimics. Treatment of Fe3(CO)12 with one equivalent of the corresponding 5-mem
Autor:
Mohammad K. Harb, Wolfgang Weigand, Hassan Abul-Futouh, Helmar Görls, Laith R. Almazahreh, Mohammad El-khateeb
Publikováno v:
Inorganic Chemistry. 56:10437-10451
The effect of the nature of the dithiolato ligand on the physical and electrochemical properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant concern. In this report we describe the cyclization of various alkanedith
Publikováno v:
Polyhedron. 106:27-31
Treatment of the in situ generated Me2NCSSeNa with (PPh3)2NiBr2 in degassed MeCN or THF gave a violet complex (PPh3)Ni(Br)(κ2S,Se-SSeCNMe2) (1). Attempts to crystalize the salt Me2NCSSeNa produced the dimeric compound (Me2NCSSe)2 (2). Complex 1 was
Autor:
Hassan, Abul-Futouh, Laith R, Almazahreh, Mohammad Kamal, Harb, Helmar, Görls, Mohammad, El-Khateeb, Wolfgang, Weigand
Publikováno v:
Inorganic chemistry. 56(17)
The effect of the nature of the dithiolato ligand on the physical and electrochemical properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant concern. In this report we describe the cyclization of various alkanedith
Autor:
Jean Talarmin, Philippe Schollhammer, Ulf-Peter Apfel, Helmar Görls, Laith R. Almazahreh, Mohammad El-khateeb, Manfred Rudolph, Wolfgang Weigand, Wolfgang Imhof
Publikováno v:
Organometallics. 32:4523-4530
A novel [FeFe]-hydrogenase model complex containing phosphine oxide in the dithiolato ligand, namely [Fe2(CO)6][(μ-SCH2)2(Ph)P═O] (1), has been synthesized and characterized. Complex 1 was prepared via the reaction of equimolar quantities of (μ-L
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 639:1512-1519
[FeFe] hydrogenase model complexes [Fe(CO)3]2[(μ-ECH2)2C(CH2OH)2] (E = S (1) or Se (2)) containing CH2OH bridgehead substituents were synthesized via reaction of equimolar amounts of 4, 4-bis(hydroxymethyl)-1, 2-dithiolane (A) or 4, 4-bis(hydroxymet
Publikováno v:
Transition Metal Chemistry. 38:377-383
Treatment of (PPh3)2MCl2 (M = Pd or Pt) with ammonium pyrrolidinedithiocarbamate (NH4S2CNC4H8) in a 1:1 molar ratio gave (PPh3)M(Cl)(κ2S,S-S2CNC4H8) [M = Pt (1), Pd (2)]. On the other hand, the interaction of these compounds in a 1:2 [M:L] molar rat