Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Lachlan J, Watson"'
Autor:
Callum M. Inglis, Richard A. Manzano, Ryan M. Kirk, Manab Sharma, Madeleine D. Stewart, Lachlan J. Watson, Anthony F. Hill
Publikováno v:
Molecules, Vol 28, Iss 23, p 7761 (2023)
A convenient synthesis of [HB(HImMe)3](PF6)2 (ImMe = N-methylimidazolyl) is decribed. This salt serves in situ as a precursor to the tris(imidazolylidenyl)borate Li[HB(ImMe)3] pro-ligand upon deprotonation with nBuLi. Reaction with [W(≡CC6H4Me-4)(C
Externí odkaz:
https://doaj.org/article/81ea30917c214755bbcf0c1bfc56d0fb
Autor:
Lachlan J. Watson, Anthony F. Hill
Publikováno v:
Dalton Transactions. 52:2164-2174
The pro-ligands 1,8-bis(di-R-phosphinomethyl)-2,3-dihydroperimidine (RH2Pm, R = phenyl, cyclohexyl) react with [RhCl(CE)(PPh3)2] (E = O, S) to afford the bimetallic complexes [RhCl(CE)(μ-RH2Pm)]2 (E = O, S).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::77862ba372a98af67734348f999fa65a
https://doi.org/10.1039/d2dt03984b
https://doi.org/10.1039/d2dt03984b
Publikováno v:
Dalton Transactions. 51:17354-17360
In-flow photochemical methods allow the convenient synthesis ‘on-demand’ of ubiquitous tetrahydrofuran organometallic solvento complexes, e.g., [M(THF)(CO)5] (M = Cr, Mo, W) and [M(THF)(CO)2(η-L)] (M = Mn, Re; L = C5H5, C5H4Me, C5Me5).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6367989648e66e8720fcab84c6e52d56
https://doi.org/10.1039/d2dt02583c
https://doi.org/10.1039/d2dt02583c
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(45)
Photolysis under optimised flow conditions of metal carbonyls [{L
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::b4ccbea9bb9aa67d514bb5a17f0aa5f6
https://pubmed.ncbi.nlm.nih.gov/36321749
https://pubmed.ncbi.nlm.nih.gov/36321749
Publikováno v:
Chemistry – A European Journal. 26:12706-12716
In contrast to the ubiquity of transition-metal carbonyl, and (to a lesser extent) thiocarbonyl complexes, transition-metal complexes of carbon monoselenide Ln MCSe and monotelluride Ln MCTe remain scarce. The last few years, however, have seen notab
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f0a7f7b1c7f030510fbb1bd8e2fe33d8
https://doi.org/10.1002/chem.202001588
https://doi.org/10.1002/chem.202001588
Autor:
Anthony F. Hill, Lachlan J. Watson
Publikováno v:
Chemical Communications. 56:2356-2359
The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4f5ff050e74cf431a5c9104aebf471c8
https://doi.org/10.1039/c9cc08172k
https://doi.org/10.1039/c9cc08172k
Publikováno v:
Angewandte Chemie International Edition. 58:15349-15353
The first examples of bi- and polynuclear tellurocarbonyl complexes were obtained from the reactions of [W(≡CTe)(CO)2 (Tp*)]NEt4 (Tp*=hydrotris(dimethylpyrazolyl)borate) with [MCl(PCy3 )]/TlPF6 (M=Cu, Au) or [Au2 Cl2 (μ-dppm)], which afford [WM(μ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d48b6890a2e87dbb6135387faecd117
https://doi.org/10.1002/anie.201909333
https://doi.org/10.1002/anie.201909333
Publikováno v:
Chemistry – A European Journal. 26
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b28790dbf2f1f70cc105797edd514d2e
https://doi.org/10.1002/chem.202085662
https://doi.org/10.1002/chem.202085662
Publikováno v:
Chemical communications (Cambridge, England). 55(96)
Novel bis(isoselenocarbonyl) complexes [W2Pt(μ-CSe)2(CO)4(L2)(Tp*)2] (L2 = cyclooctadiene, norbornadiene) eliminate the diene upon heating to provide [W2Pt(μ-CSe)2(CO)4(Tp*)2], in which the CSe ligands close to bridge W-Pt bonds in a σ-π mode tha
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08643937b86795b3bec86e1e31f6b892
https://pubmed.ncbi.nlm.nih.gov/31728473
https://pubmed.ncbi.nlm.nih.gov/31728473
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 48(33)
The new tungsten selenocarbonylate [NEt4][W(CSe)(CO)2(Tp*)] (Tp* = hydrotris(dimethylpyrazolyl)borate) reacts with group 11 reagents to provide σ–π or isoselenocarbonyl complexes of the form [WM(μ-CSe)(CO)2(PR3)n(Tp*)] (M = Cu, Ag, Au; R = Ph, C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33e1cab2c0c7cb34e583a5ebff9d13b9
https://pubmed.ncbi.nlm.nih.gov/31372618
https://pubmed.ncbi.nlm.nih.gov/31372618