Zobrazeno 1 - 10
of 220
pro vyhledávání: '"L.C. Van Poucke"'
Autor:
L.C. Van Poucke, Z. Eeckhaut
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 81:363-366
The stability constants of the Ag(I) complexes of nine amino-alcohols have been determined at 25.0±0.1 ° and in an ionic medium of 0.5 M KNO3. Because of the high values of k2/k1 the formation curves are very steep and it was preferable to calculat
Autor:
L.C. Van Poucke, M. A. Herman
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 77:487-495
The mixed complexes between Ni(II), ethylenediamine (A) and the β-alaninate ion (B) are studied in 0.5 M K.NO3 at 25 °C. The existence of NiAB+ and NiA2B+ is proved and the stability constants of these complexes are given. The visible and near-infr
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 81:357-362
The acidity constants of the ω-aminosulphonates NH2(CH2)SO3− with n = 2, 3,4 and 5 and the stability constants of the Ag(I) complexes of these ligands were determined at 25°, in 0.5 M KNO3. The enthalpy- and entropy changes accompanying the forma
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 79:611-616
The acidity constants of the ω-aminocarboxylic acids with n = 1,2,3,4,5 and the stability constants of the Ag(I) complexes of the corresponding aminocarboxylates were determined at 0°, 15° and 40°C in o.5 M KNO3. From this and the same data at 25
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 95:385-398
A procedure is described which permits the determination of magnesium (< 4% (w/w)) and calcium (< 1% (w/w)) in zirconium dioxide by atomic absorption spectrometry. Two different dissolution methods are used and evaluated. In the first method the ZrO2
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 101:267-277
A description is given for the combination of techniques for the study of the oxidative degradation of polystyrene samples with different additives. Thermogravimetry is used for the determination of the degradation profile (weight loss versus tempera
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 101:187-192
The decomposition of the oxalateprecursors Y2(C2O4)3.4BaC2O4. (6 + n)CuC2O4. xH2O for the synthesis of high Tc superconductors and the individual Y-, Ba-, Cu-oxalate components is investigated by DTA and by TGA coupled with FTIR.
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 90:357-365
A procedure is described for the determination of tin, lead, bismuth, copper, iron, silver, cadmium and zinc in Sn-Pb alloy, composed of ca. 50% Sn, 47% Pb, and 3% Bi, by means of atomic absorption spectrophotometry. The sample is dissolved in aqua r
Autor:
L.C. Van Poucke, J. Vliegen
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 87:837-843
Because of its biochemical interest the self-association behaviour of six natural occuring L-amino acids was studied by potentiometry in aqueous solutions of 3M KCl. The investigated amino acids were glycine, L-alanine, L-proline, L-hydroxyproline, L
Autor:
L.C. Van Poucke, K. Van Werde, G. Vanhoyland, M. K. Van Bael, Jules Mullens, H. Den Rul, D. Mondelaers
Publikováno v:
Journal of Materials Science. 42:624-632
Starting from a novel water-based Zr(IV)-peroxo-citrato solution, an entirely aqueous solution-gel synthesis of Pb(Zr0.53,Ti0.47)O3 (PZT) was carried out. Because of the tendency of Zr4+-ions to hydrolyze and condensate extensively in water, the Zr4+