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Publikováno v:
Tetrahedron. 57:1129-1137
The 1,3-dipolar cycloadditions of various azomethine ylides to 2-oxoindolin-3-ylidene derivatives have been investigated. The structure and stereochemistry of cycloadducts were studied in detail by NMR spectroscopic methods.
Publikováno v:
Synthetic Communications. 30:4221-4231
The electronpoor double-bond of cyclic vinylphosphine oxides (1, 3 and 4) is easily reduced by borane in a selective manner to give the corresponding saturated derivatives (2, 4 and 5, respectively) Under forcing conditions, change of the functionali
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 38:435-443
Azacrown ethers with phosphonoalkyl-and phosphinoylalkyl side chains of two to five carbonatoms (2–4, 7 and 5–6, 8,respectively) were synthesized in acceptable yields.The cation binding ability of the new lariat etherswas evaluated by the picrate
Autor:
Krisztina Ludányi, L. Toke, Tibor Novák, Klára Tóth, Péter Bakó, Kálmán Újszászy, György Keglevich
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 34:299-309
The synthesis of azacrown ethers with phosphonoalkyl side chains of two to five carbon atoms ( 3–8, 10), potentially useful as a new type of cation binding agent, is described. Introduction of the phosphonoalkyl moiety into the parent monoaza-15-cr
Publikováno v:
Thermochimica Acta. 319:87-95
Solid samples prepared from benzo-15-crown-5, its nitro, acetylamino and decanoylamino derivatives (Group I), and chloro-dibenzo-aza-crown ethers (Group II) with alkali metal salts were studied. The existence of solid adducts between LiBr, NaSCN, KSC
Publikováno v:
Tetrahedron. 54:11597-11602
( E )-1-benzyloxy-2,3-epoxyalkanes ( 4 ) underwent stereoselective rearrangement in the presence of LIDAKOR reagent and large excess of butyllithium producing ( Z )-alkendiols (7) at ambident temperature. The same reaction serves anti oxetanes (6) at
Publikováno v:
Tetrahedron: Asymmetry. 9:2293-2299
The isomerization of alkoxy oxiranes with chiral lithium amides has been carefully investigated with the aim of finding an enantioselective approach to hydroxy enolethers, a class of compounds which can be used for further synthetic elaborations.
Publikováno v:
Tetrahedron. 54:213-222
Crown ethers anellated to glucose units have been used to catalyse the enantioselective Michael addition of methyl phenylacetate to methyl acrylate in high chemical yields in up to 84% enantiomeric excess. A novel CH-acid deracemization has also been
Publikováno v:
Scopus-Elsevier
A new annelation sequence was developed for the bicyclic diones2, intermediates in the total synthesis of strigol (1) and its analogues. The first step of the sequence is the conjugate addition of nitro alcohols4 to cyclopentenone5, followed by an al