Zobrazeno 1 - 2
of 2
pro vyhledávání: '"L. R. Grigorʼeva"'
Autor:
D. V. Ponomaryov, O. V. Tsepaeva, Vladimir F. Mironov, A. V. Nemtarev, L. R. Grigorʼeva, O. I. Gnezdilov, Igor S. Antipin
Publikováno v:
Russian Journal of Organic Chemistry. 56:626-630
A convenient procedure has been developed for the synthesis of 3β,28-diacetoxylup-20(29)-en-30-oic acid via oxidation of 3β,28-di-O-acetylbetulin with selenium dioxide in aqueous ethanol on heating, followed by oxidation of 3β,28-diacetoxylup-20(2
Autor:
Igor S. Antipin, A. V. Nemtarev, Vladimir F. Mironov, D. V. Ponomaryov, O. V. Tsepaeva, L. R. Grigor´eva
Publikováno v:
Russian Chemical Bulletin. 69:487-491
3β,28-Diacetoxylup-20(29)-en-30-oic acid (obtained via oxidation of betulin diacetate) enters the addition reaction with P—H-phosphonium salts (triarylphosphonium trifluoroacetates) under mild conditions to afford β-carboxyalkylphosphonium salts.