Zobrazeno 1 - 10
of 35
pro vyhledávání: '"L. M. Pisarenko"'
Publikováno v:
Russian Journal of Physical Chemistry B. 14:773-780
Colloidal particles of iron hydroxide produced by the hydrolysis of an iron(III) chloride solution in hot water catalyze the consumption of hydrogen peroxide and initiate the oxidative decomposition of impurities present in technical cellulose. This
Autor:
L. M. Pisarenko
Publikováno v:
Russian Chemical Bulletin. 67:1026-1030
The catalytic activity of the colloidal catalyst based on iron(III) hydroxide was studied in the decomposition of H2O2 in a neutral medium (pH 6.7). A colloidal micellar solution of iron(III) hydroxide after preparation was kept at 19–20 °С for 2
Publikováno v:
Kinetics and Catalysis. 58:556-562
The peculiarities of the catalytic action of cationic surfactants (CSurf) in combination with hydroperoxides on the generation of radicals and the influence of various factors on this process (transition metal compounds, oxygen, and external magnetic
Autor:
O. T. Kasaikina, L. M. Pisarenko
Publikováno v:
Russian Chemical Bulletin. 64:2319-2324
The retardation effect of oxygen and external magnetic field on the yield of radicals in hydroperoxide decomposition in catalytic nanoreactors was discovered. Mixed reverse micelles formed by the cationic surfactants (Surf) and hydroperoxide {mLOOH..
Publikováno v:
Russian Chemical Bulletin. 63:688-692
The catalyst based on iron(iii) oxides was prepared by hydrolising FeIII salt in water and adding surfactants. The catalyst is active in decomposing H2O2 and accelerates the oxidative destruction of ligno-containing biomass at atmospheric pressure an
Publikováno v:
Colloid Journal. 74:85-90
The catalytic activity of a colloidal catalyst based on iron(III) oxides in decomposition of H2O2 is studied. The catalyst is obtained by hydrolysis followed by peptization of FeCl3 · 6H2O salt in water in the presence of 1% ethanol. The structure,
Publikováno v:
Moscow University Chemistry Bulletin. 65:206-209
The features of the catalytic effects of surfactants (S) in the oxidation of hydrocarbons and lipids are considered. It is shown that the primary amphiphilic products of the oxidation of hydroperoxides (ROOH) and lipids and the known cationic surfact
Publikováno v:
Russian Journal of General Chemistry. 78:1533-1544
A review is presented compiling new data on liquid-phase oxidation of hydrocarbons and plant oils in microheterogeneous environment formed by the addition of surfactants. Cationic surfactants catalyze the decomposition of the primary oxidation produc
Publikováno v:
Russian Chemical Bulletin. 57:83-89
The kinetic regularities of the autooxidation of R(+)−limonene (LH) were experimentally studied at various temperatures. A kinetic model including the main elementary reactions and the corresponding rate constants was developed. The degenerate chai
Publikováno v:
Russian Chemical Bulletin. 54:1855-1861
The features of cumene oxidation, α-phenylisopropyl hydroperoxide (ROOH) decomposition, and free radical formation in the presence of cetyltrimethylammonium bromide (CTAB) were studied by the kinetic methods and TLC product analysis. It was found th