Zobrazeno 1 - 10
of 30
pro vyhledávání: '"L. M. Épshtein"'
Publikováno v:
Pharmaceutical Chemistry Journal. 30:510-512
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1131-1135
1. A study was made of the absorption bands In the 1500–1750-cm−1 region of the spectra of o-carbonylcontaining phenols, and their phenylmercury and triethyltin derivatives, in polar and nonpolar solvents. 2. It has been shown that the carbonyl g
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:242-246
1. The position of the tautomeric equilibrium for 2-substituted nitrosophenols and their organometallic derivatives in toluene is related to the ability of the OH and RnMO groups to form chelate rings with a halogen atom or MeO group. The stabilizati
Autor:
D. A. Bochvar, L. A. Kazitsyna, Nina P Gambaryan, A. N. Zhdanova, N. S. Dolgopyat, L. M. Épshtein
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:2302-2307
1. The electron-donor properties of RnXNR2-type compounds, where X=S, Se, P, or As, decrease relative to a series of H acids in the order NR3≫R2NXRn>XRn+1. 2. The donor properties of bidentate bases increase on replacement of a Period III hetero at
Autor:
V. L. Beloborodov, D. N. Kravtsov, L. S. Golovchenko, L.A. Kazitsyna, L.D. Ashkinadze, L. M. Épshtein
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1573-1579
1. Electronic spectroscopy has been used to show the similarity of the reactions of the nitrophenols and their phenylmercury and triphenyltin derivatives with triethylamines and diethylamines. 2. Increasing the electron-acceptor activity of the aroma
Publikováno v:
Russian Chemical Reviews. 45:660-670
Comparison of non-empirical calculations on analogous nitrogen and phosphorus compounds shows that the presence of vacant d orbitals in the valence shells of the elements in the Third Period cannot be the real cause of the differences between the pro
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:1836-1840
1. Measurements have been made of the Raman line intensities at 1600 cm−1, and electronic spectra developed for diphenyl and triphenyl derivatives of group V and VIb elements, respectively. 2. Neither the change in intensity of the Raman line, nor
Autor:
L. A. Kazitsyna, S. I. Pombrik, L. D. Ashkinadze, V. L. Beloborodov, E. M. Rokhlina, L. M. Épshtein, D. N. Kravtsov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1585-1591
1. Comparison of electronic spectra has brought out the effect of polar and conformational factors in the behavior of the organometallic derivatives of the nitrophenols and nitrothiophenols. 2. Interaction of these compounds with DMSO does not lead t
Autor:
L. D. Ashkinadze, V. L. Beloborodov, L. M. Épshtein, D. N. Kravtsov, L. S. Golovchenko, E. M. Rokhlina, L. A. Kazitsyna
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1815-1820
1. Study has been made of the IR and UV spectra of various substituted o-nitrophenols and o-nitrothiophenols, and their organomercury and organolead derivatives, in polar and nonpolar solvents. Constants for the complexing of these compounds with pyr
Autor:
L. S. Golovchenko, V. M. Pachevskaya, Zyong Fan Dau, D. N. Kravtsov, L. A. Kazitsyna, L. M. Épshtein
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2334-2339
1. Exchange equilibria of the metal-proton and metal-metal type were studied by the method of IR spectroscopy in a series of substituted phenols and their C6H5Hg and (C6H5)3Sn derivatives. 2. The polar effects of substituents in the phenol ring chang