Zobrazeno 1 - 10
of 28
pro vyhledávání: '"L. Lobeck"'
Autor:
Patrick A. Julien, Hrafn Traustason, Haylie L. Lobeck, Mateusz Dembowski, Peter C. Burns, Mengyu Xu
Publikováno v:
Inorganic Chemistry. 60:6753-6763
The solution behavior of a polyoxometalate cluster, LiNa-U24Pp12 (Li24Na24[(UO2O2)24(P2O7)12]) that consists of 24 uranyl ions, peroxide groups, and 12 pyrophosphate linkers, was successfully predicted based on new thermodynamic results using a calor
Autor:
Mengyu Xu, Peter C. Burns, Jordan K. Isner, Sara Boukdad, Henry M. Ridder, Ewa A. Dzik, Haylie L. Lobeck, Tsuyoshi A. Kohlgruber, Enrica Balboni, Hrafn Traustason, Connor J. Parker
Publikováno v:
American Mineralogist. 105:182-193
Uranyl phosphate minerals are widespread in uranium deposits and normally exhibit very low solubility in aqueous systems. Uranyl phosphates of the autunite group and metaautunite subgroup impact the mobility of uranium in the environment and have ins
Publikováno v:
Journal of Solid State Chemistry. 276:56-60
The syntheses, characterization, and calorimetric measurements of enthalpies of formation of four tetravalent metal sulfate tetrahydrates (A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U): α-Zr(SO4)2(H2O)4, α-Ce(SO4)2(H2O)4, β-Ce(SO4)2(H2O)4, and β-U(SO4)2(H2O)
Publikováno v:
Inorganic Chemistry. 58:6781-6789
The dissolution behavior of uranyl peroxide studtite, [(UO2)(O2)(H2O)2](H2O)2, was examined under a wide range of alkaline aqueous environments with and without the addition of hydrogen peroxide. In the absence of added H2O2, studtite dissolved in aq
Autor:
Hrafn Traustason, Jennifer E. S. Szymanowski, Sara Mana, Peter C. Burns, Haylie L. Lobeck, Patrick A. Julien, John R FitzPatrick
Publikováno v:
Dalton Transactions. 48:7755-7765
Aqueous solutions containing the nanoscale uranyl peroxide cage clusters U60, [(UO2)(O2)(OH)]6060-, and U60Ox30, [{(UO2)(O2)}60(C2O4)30]60-, were monitored by in situ Raman spectroscopy during stepwise heating to 180 °C. In solutions containing U60,
Publikováno v:
Chemical Geology. 493:353-358
Five uranyl arsenates of the meta-autunite group with mono (Li, K, Cs) and divalent (Sr and Cu) cations were synthesized at room temperature and characterized. Their thermodynamic properties were measured using high-temperature oxide melt calorimetry
Publikováno v:
The Journal of Chemical Thermodynamics. 114:165-171
Samples of synthetic analogs of uranyl phosphate minerals have been prepared at room temperature by slow mixing of reactants by a diffusion method. Reaction products were analyzed using powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA
Publikováno v:
American Mineralogist. 102:1977-1980
Autunite, Ca[(UO 2 )(PO 4 )] 2 (H 2 O) 11 , is a common uranyl mineral found in oxidized portions of uranium deposits, as well as subsurface environments contaminated by uranium. Enthalpies of formation of autunite were obtained via high-temperature
Publikováno v:
Inorganic chemistry. 58(10)
The dissolution behavior of uranyl peroxide studtite, [(UO