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Publikováno v:
The Journal of Physical Chemistry B. 102:7714-7720
Evolutive dissipative structures were observed during UV irradiation of the surface of acrylate films leading to photopolymerization. Self-organization results in the formation of hexagonal or square cells, waves, stars, and spots. These different si
Publikováno v:
Pure and Applied Optics: Journal of the European Optical Society Part A. 6:225-245
The diffusion mechanism for hologram formation in multicomponent polymerizable systems undergoing photocrosslinking was examined. The nonlinear diffusion equation was solved to predict the behaviour of the recording system. The results show the cruci
Autor:
D.-J. Lougnot, L. Lavielle
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 102:245-251
Space and time instabilities can appear as very general phenomena at the surface of liquid or viscous films submitted to constraints. In the case of dry photopolymerized acrylate films, the surface relief at the monomer-polymer interface is examined
Autor:
L. Lavielle, A. Sanfeld
Publikováno v:
Electrochimica Acta. 41:2079-2088
An extended thermodynamic Gibbs equation for oriented surface rigid dipolar molecules allows the comparison of theoretical and experimental results on grafted polymers in contact with water. Furthermore, the analysis of orientation process kinetics s
Autor:
L. Lavielle, Saad Lamouri
Publikováno v:
Journal of Synthetic Lubrication. 12:125-131
The friction of pure polyethylene and acrylate grafted films or mixtures of polyethylene and a poly (ethylene-butylacrylate-maleic anhydride) terpolymer is examined at low speed for sliding on a poly(methylmethacrylate)(PMMA) or polyvinylchloride (PV
Autor:
L. Lavielle
Publikováno v:
Wear. 176:89-93
Friction properties of polyethylene-terpolymer films rubbing on a steel substrate have been examined as a function of the electric field effect. It appears clearly that adhesion at the interface is modified by the presence of the field. This leads to
Publikováno v:
Journal of Applied Polymer Science. 46:1045-1050
Application of a high continuous electrical field accelerates the orientation kinetics of polar groups at a polymer-water interface and so improves the surface polarity. This is preliminary to adhesion establishment on a polar substrate. Adhesion of
Publikováno v:
Journal of Materials Science: Materials in Medicine. 3:387-390
Poly(methyl methacrylate) is widely used in dentistry. In contact with water, there is an increase in the polar surface free energy from 9.5 to 21 mJ m−2. Various other surface modification treatments have been examined (chemical treatment, gold de
Autor:
L. Lavielle
Publikováno v:
Wear. 157:181-187
A wide variety of friction coefficients can be obtained with mixtures of polyethylene and (polyethylene-butylacrylate-maleic anhydride) terpolymers as films rubbing on smooth polymer substrates (poly(vinyl chloride), polymethylmethacrylate). Owing to