Zobrazeno 1 - 10
of 79
pro vyhledávání: '"L. I. Ukhova"'
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 24
Publikováno v:
Chemistry of Natural Compounds. 27:400-403
A method is proposed for introducing one, two, or three alkyl substituents into positions 4 and 6 of the cyclohexane-1, 3-dione molecule by successive alkylation under the action of strong bases. (±)-Angustione (a natural β-diketone) has been synth
Publikováno v:
Chemistry of Natural Compounds. 26:519-524
The synthesis of (±)-angustione has been carried out on the basis of a method that we have developed for the regio- and stereoselective alkylation of enaminodiketones of the cyclohexane series.
Autor:
A. A. Govorova, N. F. Marchenko, A. A. Akhrem, V. A. Tereshko, A. I. Verenich, N. M. Galitskii, L. I. Ukhova
Publikováno v:
Chemistry of Heterocyclic Compounds. 29:71-73
The results of x-ray diffraction analysis on 1,2e-dimethyl-4a-ethynyl-4e-hydroxy-trans-decahydroquinoline N-oxide hydrobromide corroborated the orientation of the substituents at the nitrogen atom that was determined previously from PMR data.
Publikováno v:
Chemistry of Heterocyclic Compounds. 11:844-849
The primary fraction of the total ion current in the mass spectra of decahydro-4-quinolones and 4-alkyl-2-methyldecahydro-4-quinolols containing various substituents in the 1, 4, and 7 positions is due to fragments with ammonium ion structures.
Autor:
G. V. Bludova, A. A. Akhrem, N. I. Garbuz, L. P. Solovei, T. M. Tsvetkova, G. I. Trus, L. I. Ukhova
Publikováno v:
Chemistry of Heterocyclic Compounds. 12:90-95
Isomeric 1-alkyl-2-methyl-4- (haloethynyl) decahydro-4-quinolols were synthesized by reaction of the individual stereoisomers of 1-alkyl-2-methyl-4-ethynyl-decahydro-4-quinolols with alkali solutions of potassium hypochlorite and hypobromite. 1-Chlor
Publikováno v:
Chemistry of Heterocyclic Compounds. 13:177-180
The stereochemistry of the oxidation and alkylation of the nitrogen atom of trans-1-alkyl-4-ethynyldecahydro-4-quinolols was investigated. The orientation of the substitutents attached to the nitrogen atom in the synthesized N-oxides and quaternary s
Publikováno v:
Chemistry of Heterocyclic Compounds. 16:617-621
The spatial orientation of the hydroxy group in stereoisomeric 2,9-dimethyl- and 1,2,9-trimethyldecahydro-4-quinolols and their 4-ethynyl-substituted derivatives was established by IR spectroscopy. The formation of an intramolecular hydrogen bond in