Zobrazeno 1 - 10
of 15
pro vyhledávání: '"L. H. Chopard‐dit‐Jean"'
Publikováno v:
Helvetica Chimica Acta. 42:772-788
Rac. 2-dehydro-emetine (XV) and rac. 2-dehydro-isoemetine (XVI) have been synthesized in five steps and in good yield from 2-oxo-3-ethyl-9,10-dimethoxy-l, 2,3, 4,6,7-hexahydro-11bH-benzo [a]chinolizine (VII). Homologues and analogues of XV and XVI wi
Publikováno v:
Helvetica Chimica Acta. 41:1793-1806
Publikováno v:
Helvetica Chimica Acta. 41:786-807
The structure of vitamin K2, m. p. 54°, is established as 2-methyl-3-all-trans-farnesylgeranylgeranyl-1,4-naphtoquinone by total synthesis and comparison of the synthetic compound with vitamin K2 from putrefied fish meal. It contains a terpenoid sid
Autor:
E. Heilbronner, L. H. Chopard‐dit‐Jean
Publikováno v:
Helvetica Chimica Acta. 36:144-160
Das Azulen, die funf isomeren Monomethyl-azulene und einige polyalkyl-substituierte Azulene wurden polarographiert. Alle zeigen ein mehrstufiges Polarogramm, dessen erste Stufe auf den Verbrauch eines einzigen Elektrons bei der Reduktion hinweist. Im
Autor:
L. H. Chopard‐dit‐Jean, K. Vogler
Publikováno v:
Helvetica Chimica Acta. 43:279-286
(+)-6-Methyloctanoic (isopelargonic) acid, the fatty acid component of certain polypeptide antibiotics known as polymyxins, has been synthesized by a new route, starting from (−)-2-methylbutanol-(1). The protected dipeptide Nα-(+)-Isopelargonyl-N
Publikováno v:
Helvetica Chimica Acta. 42:1283-1292
The isolation of a new quinone from leaves is described. Its structure has been established as an o-dimethylbenzoquinone derivative with a vitamin K2-like isoprenoid side chain of 50 carbon atoms.
Publikováno v:
Helvetica Chimica Acta. 37:1872-1885
A semi automatic titration apparatus is described with which microtitrations using about 1 mg of a compound of equivalent weight 300 may be carried out. A statistical analysis of the apparatus using benzoic acid as a test substance has been carried o
Publikováno v:
Helvetica Chimica Acta. 40:1256-1262
11,11′-Di·cis-β-carotene was synthesized awarding to a new scheme C14 + C12 + C14 = C40 by condensing the crystalline C12-di-acetylenic hydrocarbon 3,8-dimethyl-decatriene-(3,5,7)-diyne-(9) at both ends with β-C14-aldehyde followed by dehydratio
Publikováno v:
Helvetica Chimica Acta. 45:548-561
The physical properties of 6 vitamin A2 isomers are reported and compared with those of the corresponding vitamin A isomers.
Autor:
O. Schindler, R. A. Morton, U. Gloor, F. W. Hemming, Otto Isler, G. M. Wilson, Rudolf Ruegg, J. F. Pennock, Ulrich Schwieter, W. M. F. Leat, O. Wiss, L. H. Chopard‐dit‐Jean
Publikováno v:
Helvetica Chimica Acta. 41:2343-2357
The isolation in pure form of the ubiquinone from pig heart is described. From 750 kg raw material 37 g of pure crystalline material could be obtained. Its structure has been established as that of a 2,3-dimethoxy-5-methyl-benzoquinone derivative wit