Zobrazeno 1 - 7
of 7
pro vyhledávání: '"L. E. Turkin"'
Publikováno v:
Kinetics and Catalysis. 51:348-353
The rate constant of the reaction between iodomethane and chlorine atoms at 323 K, measured by the resonance florescence method under jet stream conditions as the iodine atom yield, is k 1 I = (2.9±0.6) × 10−12 cm3 molecule−1 s−1. It is demon
Publikováno v:
Kinetics and Catalysis. 51:1-5
The reaction of hydrogen sulfide with ozone at 343 K was studied in a flow reactor whose inner surface was coated with 32-L fluoroplastic both immediately after coating and after repeatedly treating with reaction products (sulfur compounds). In the l
Publikováno v:
Kinetics and Catalysis. 50:474-480
The following reaction rate constants of oxygen atoms with iodomethane and chlorine were measured using resonance fluorescence under jet conditions at 298 K: k 1 = (2.4 ± 0.5) × 10–15 and k 2 = (6.9 ± 0.2) × 10−14 cm3/s, respectively.
Publikováno v:
Kinetics and Catalysis. 48:620-625
A jet-stream kinetic technique and the resonance fluorescence method applied to detection of iodine atoms were used to measure the rate constants of the reactions of the IO· radical with the halohydrocarbons CHFCl-CF2Cl (k = (3.2 ± 0.9) × 10−16
Publikováno v:
Kinetics and Catalysis. 48:1-7
The reaction between hydrogen iodide and ozone at 295 K has been investigated by the resonance fluorescence method applied to the detection of iodine atoms. A chain mechanism is suggested for this reaction. The chain initiation rate constant is k1 =
Publikováno v:
Kinetics and Catalysis. 44:202-210
The reaction of iodine monoxide with chlorine monoxide resulting in atom escape to the gas phase is studied at T = (303 ± 5) K and P = 2.5 Torr using a flow setup for measuring the resonance fluorescence signals of atomic iodine and chlorine. The he
Publikováno v:
Kinetics and Catalysis. 41:437-443
The reactions of iodine monoxide (IO•) with sulfur-containing compounds, which are important for the atmospheric chemistry, are studied. An attempt is made to distinguish between the heterogeneous and homogeneous reaction pathways. It is shown that