Zobrazeno 1 - 4
of 4
pro vyhledávání: '"L. E. Melbardis"'
Publikováno v:
Russian Chemical Bulletin. 43:953-956
The interaction of 3,6-di-tert-butyl-2-hydroxyphenoxyl with triethylamine in the reaction of proton transfer is catalyzed by water. However, the rate of proton exchange with diethylamine is independent of water admixtures in the reaction medium. ESR
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8b73aa35d62e7e1d4a22f1cb65ca3a52
https://doi.org/10.1007/bf01558055
https://doi.org/10.1007/bf01558055
Publikováno v:
Russian Chemical Bulletin. 42:74-77
The mechanism of proton exchange between semiquinone neutral radicals 3,6-di-tert-butyl-2-hydroxyphenoxyl (1), 6-tert-butyl-3-chloro-2-hydroxy-4-triphenylmethylphenoxyl, and hydrochloric acid in toluene solutions has been studied. The rate of proton
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e8c5093748f60feae59e58c4d63a132c
https://doi.org/10.1007/bf00699978
https://doi.org/10.1007/bf00699978
Publikováno v:
Russian Chemical Bulletin. 42:71-74
Thermodynamic and kinetic acidities of 6-tert-butyl-2-hydroxy-4-triphenylmethylphenoxyl during its interaction with triethylamine in toluene have been studied by ESR. It has been shown that the protolysis of this radical is a two-pathway process, sin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aaa283987aa4393f628a6de1c4e4c51a
https://doi.org/10.1007/bf00699977
https://doi.org/10.1007/bf00699977
Publikováno v:
Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1975-1978
The kinetic acidity of 2,6-di-tert-butyl-4-hydroxyphenoxyl in tetrahydrofuran has been estimated by means of ESR. It is shown that ion pairs are formed in the process of proton transfer from the radical to triethylamine.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1359608a570afbb63be4e812a82d9933
https://doi.org/10.1007/bf00863358
https://doi.org/10.1007/bf00863358