Zobrazeno 1 - 10
of 47
pro vyhledávání: '"L. Degols"'
Autor:
L. Degols, Georges Liénard
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 99:817-831
Reaction of ethane over rhodium model catalyst is studied using a method combining non steady‐state transient effect and labelling with a large excess of deuterium. Relaxation of the catalytic system after an ethane pressure jump as well as rates a
Autor:
L. Degols, Georges Liénard
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 99:803-815
A method is described to acquire, in addition to catalytic reaction rates, the reactant adsorption rate, the surface coverage and its rate of formation. It is based on a non steady‐state transient technique, initiated by a pressure step of one reac
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 98:49-62
The kinetics of ethane hydrogenolysis catalysed by Rh powder is studied in a very wide range of experimental conditions: 10 torr < PH2 < 1400 torr; 147°C < T < 245°C; 10torr < PC2H6 < 500torr. The results are compared with previously published resu
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 88:631-639
According to a model of “landing site” for chemisorption of alkanes on metal in presence of H2, previously published, the hydrocarbon adsorption rate is proportional to a function G of the H coverage (ΘH). The observed variations with H2 pressur
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 88:621-630
About ten years ago, some catalytic reactions were termed “demanding reactions” by Boudart who three years later also introduced the concept of “structure sensitive reactions”. As time passed, the two terms were confounded because the reactio
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 102:23-38
Publikováno v:
Journal of Molecular Catalysis. 59:257-266
Supported catalysts containing chlorine originating from the precursor salt used in preparation have been shown previously to exhibit two features towards hydrogen adsorption not found in model catalysts: (1) a very important slow adsorption (2) a ve
Publikováno v:
Journal of Clinical Oncology. 23:8271-8271
8271 In 2003 and 2004 Marx and Ruggerio defers 36 and 63 cases Osteonecros of the jaws (ONJ).Durie reported at the ASH 162 cases according to data’s of the WEB. The principal factor of risk is diph...
Publikováno v:
Catalysis Today. 5:223-236
Hydrogen adsorption is studied on two Rh/Al2O3 catalyst: 1.04% Rh(∼100% dispersion) and 4.8% Rh (
Publikováno v:
Journal of Catalysis. 35:18-23
Interpretation of ethane hydrogenolysis results, considering that the carbon-carbon bond breaking is rate determining on almost all studied metallic catalysts, is criticized. Comparison with methane deuterium exchange results and interpretations sugg