Zobrazeno 1 - 10
of 250
pro vyhledávání: '"L. De Buyck"'
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 84:371-380
Bromination of isophorone with excess of bromine in carbon tetrachloride at 0° gave 2,4,6-tribromo-3-bromomethyl-5, 5-dimethyl-2-cyclohexenone which on further treatment with bromine afforded 2,4,6, 6-tetrabromo-3-bromomethyl-5, 5-dimethyl-2-cyclohe
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 89:57-65
A series of dihydrobenzo [a] xanthone derivatives has been prepared by thermal condensation of 2-ethoxycarbonyl-3,4-dihydro-[1H]-naphtalene-1-one and 1-ethoxycarbonyl-3, 4-dihydro-[2H]-naphtalene-2-one with phenolic substrates.
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 89:441-458
A method is described for the synthesis of α,α-dichloroaldehydes, free from monochloroaldehyde, by chlorination of aldehydes or alcohols in dimethylformamide at 40–90°C. Results are reported for: (yield %) propanal (90), butanal (78), pentanal (
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 97:69-82
Cyclohexadienone 2 was obtained in 90% yield from heptachloroisophorone 1 by selective dechlorination and hydrolysis in 90% methanol containing iodide and bisulfite. Reaction of 2 with methanolic sodium methoxide allowed isolation of aldehyde 4 (95%
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 86:55-63
Reaction of dimethyl 2-bromo-2-methylpropylidene malonate with various nucleophiles mainly afforded dimethyl cyclopropane 1,1-dicarboxylates while treatment with amines gave substitution products.
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 97:525-533
Production of α,α-dichloroaldehydes by direct chlorination of 1-alkanols with chlorine gas, catalyzed by DMF and DMF. HCl, was extended to long chain compounds (CnH2n+1OH; n = 5,6,8,10,12,14,16,18). Two problems specific to the longer chains were s
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 84:747-759
4-Hydroxybenzofuran and 5-hydroxychroman compounds have been synthesized by heating 2-chloro-2-alkenyl-1,3-cyclohexanediones, prepared by chlorination of 2-alkenyl-1,3-cyclohexanediones with N-chlorosuccinimide, in dimethylformamide -25% hydrogen chl
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 86:879-885
Reaction of N-l-(2, 2, 2-trichloroethylidene) t. butylamine with sodium alkoxides and phenoxide in methanol mainly gave the corresponding dichloroimidates, while reaction with potassium cyanide afforded a dichlorocyanoenamine. The reaction mechanisms
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 84:761-765
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 97:55-68
The reaction of 2, 6, 6-trichloro-3-dichloromethyl-5, 5-dimethyl-2-cyclohexenone (1) with triethylamine in acetic acid containing acetic anhydride afforded 2-acetoxy-6-diacetoxymethyl-3-chloro-4, 4-dimethyl-2, 5-cyclohexadienone (2) in 49% yield (47%