Mechanism of Mobile Charge Carrier Generation in Blends of Conjugated Polymers and Fullerenes: Significance of Charge Delocalization and Excess Free Energy

Autor: M. Gao, Martien J. W. Vermeulen, Tom J. Savenije, Dharmapura H. K. Murthy, L. D. A. Siebbeles

Publikováno v: The Journal of Physical Chemistry C. 116:9214-9220

Despite significant improvement in power conversion efficiencies of bulk-heterojunction solar cells, the mechanism of mobile charge carrier generation is still under debate. The time-resolved microwave conductivity technique is used to investigate th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::91d18d6df13cef3cdb6909aafb949fa4
https://doi.org/10.1021/jp3007014

Charge transport along phenylenevinylene molecular wires

Autor: P. Prins, Ferdinand C. Grozema, L. D. A. Siebbeles

Publikováno v: Molecular Simulation. 32:695-705

A model to calculate the mobility of charges along molecular wires is presented. The model is based on the tight-binding approximation and combines a quantum mechanical description of the charge with a classical description of the structural degrees

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::73fb017a01df69ad0741a008ab06cc5a
https://doi.org/10.1080/08927020600835657

Electron and Hole Dynamics on Isolated Chains of a Solution-Processable Poly(thienylenevinylene) Derivative in Dilute Solution

Autor: L. P. Candeias, A. J. J. M. van Breemen, J. Sweelssen, L. D. A. Siebbeles, H. F. M. Schoo, P. Prins, P. T. Herwig

Publikováno v: Advanced Materials. 17:718-723

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::980e61ed984ddc7d68da35244cc22c07
https://doi.org/10.1002/adma.200400879

Separation of positron beam-induced charges in polyethylene by external electric fields

Autor: A. van Veen, H. Schut, A Alba Garcı́a, L. D. A. Siebbeles

Publikováno v: Radiation Physics and Chemistry. 68:515-518

We show the results of positron beam Doppler broadening measurements on low-density polyethylene under external electric fields. It is found that long-term measurements with a moderate beam intensity of approximately 10 5 e + /s result in the accumul

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::442e2e1a438e514230e6aad0b422886e
https://doi.org/10.1016/s0969-806x(03)00247-0

Theoretical and experimental studies of the opto-electronic properties of positively charged oligo(phenylene vinylene)s: Effects of chain length and alkoxy substitution

Autor: Luis P. Candeias, J. Wildeman, P.Th. van Duijnen, Marcel Swart, John M. Warman, L. D. A. Siebbeles, G. Hadziioanou, Ferdinand C. Grozema

Publikováno v: Journal of Chemical Physics, 117, 11366-11378. American Institute of Physics Publising LLC
Journal of Chemical Physics, 117 (24), 2002
Grozema, F C, Candeias, L P, Swart, M, van Duijnen, P T, Wildeman, J, Hadziioanou, G, Siebbeles, L D A & Warman, J M 2002, ' Theoretical and experimental studies of the opto-electronic properties of positively charged oligo (phenylene vinylene)s: Effects of chain length and alkoxy substitution ', Journal of Chemical Physics, vol. 117, pp. 11366-11378 . https://doi.org/10.1063/1.1522374

In this paper a combined experimental and quantum chemical study of the geometry and opto-electronic properties of unsubstituted and dialkoxy-sustituted phenylene–vinylene oligomers (PV’s) is presented. The optical absorption spectra for PV catio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc8933b955847932f3cc8c53eb3a738b
https://doi.org/10.1063/1.1522374