Zobrazeno 1 - 10
of 373
pro vyhledávání: '"L. Abouaf-Marguin"'
Publikováno v:
Chemical Physics Letters. 480:82-85
We have measured a nuclear spin conversion time of 100 min for H 2 O highly diluted in solid xenon at 4.2 K. Compared with argon matrices, the conversion is very probably enhanced by the high natural abundance of xenon magnetic isotopes. The ν 2 mod
Publikováno v:
Chemical Physics Letters
Chemical Physics Letters, 2009, 470, pp.228-232. ⟨10.1016/j.cplett.2009.01.047⟩
Chemical Physics Letters, 2009, 470, pp.228-232. ⟨10.1016/j.cplett.2009.01.047⟩
From the IR induced spectrum between 4000 and 5000 cm −1 of solid normal hydrogen doped with H 2 O, CH 3 F, CH 4 , and double doped with O 2 , the nuclear spin conversion of ortho -H 2 molecules has been analyzed at 4.2 K. The self-conversion rate
Autor:
L. Abouaf-Marguin, A.-M. Vasserot
Publikováno v:
Chemical Physics Letters
Chemical Physics Letters, 2008, 460, pp.82-85. ⟨10.1016/j.cplett.2008.04.133⟩
Chemical Physics Letters, 2008, 460, pp.82-85. ⟨10.1016/j.cplett.2008.04.133⟩
We have studied the time evolution of IR spectra of solid normal H 2 doped with O 2 at 4.2 K. We have determined ortho concentration from IR integrated intensity ratio between the ortho double transitions at 4736 cm −1 and the para contribution to
Publikováno v:
Chemical Physics Letters. 454:61-64
We have observed the time evolution of ( o- H 2 ) n :H 2 O clusters, trapped in solid H 2 at 4.2 K over a period of 178 h, using O 2 to catalyse the ortho to para- nuclear spin conversion of solid H 2 . The clusters observed at time 0 of the experime
Publikováno v:
Low Temperature Physics. 29:852-857
Fourier-transform infrared spectroscopy in the frequency range 400–4000 cm−1 has been used to investigate the absorption of H2O and H2O:CO2 complex isolated in solid argon. Thanks to the lowest temperature reached in our experiment, temperature e
Publikováno v:
Journal of Molecular Spectroscopy. 220:201-208
Low temperature (5 K) high resolution (0.15 and 0.03 cm−1) absorption spectra of 13CO2 have been recorded in neon, argon, krypton, and xenon matrices, in the ν3 and ν2 regions. Diffusion experiments have been performed in krypton and xenon in ord
Publikováno v:
The Journal of Chemical Physics. 117:4436-4447
The ν3 vibrational mode of 13CO2, trapped in a rare gas matrix, is excited by a laser pulse near 2300 cm−1. Emission is then observed in the 16 μm region and assigned to three transitions: namely, 3ν21-2ν20, 3ν21-2ν22, and 2ν20-ν21, which a
Publikováno v:
Journal of Molecular Structure. 484:145-159
A molecular mechanics method using interaction potentials fitted on “Symmetry Adapted Perturbation Theory” calculations is applied to the determination of some structural and vibrational properties of interacting CO and CO 2 species, either in ga
Autor:
H. Chabbi, V. Raducu, Pierre-Richard Dahoo, L. Abouaf-Marguin, Azzedine Lakhlifi, I. Berrodier, J.L. Teffo
Publikováno v:
The European Physical Journal D - Atomic, Molecular and Optical Physics. 5:71-81
FTIR spectra of the antisymmetric stretch \(\) and symmetric bending \(\)vibrational modes of isotopic species of CO2 trapped in argon matrix are recorded at 5 K with a resolution of \(\). A splitting of the \(\) mode is observed for the different sp
Publikováno v:
The Journal of Chemical Physics. 108:8541-8549
A time resolved infrared–infrared double resonance technique is used to study the vibrational relaxation of O3 in rare gas and nitrogen matrices. A tunable infrared (IR) pulsed source excites the ν1+ν3 level of O3 in the ground electronic state.