Zobrazeno 1 - 10
of 21
pro vyhledávání: '"L. A. Khanova"'
Autor:
Lev I. Krishtalik, L. A. Khanova
Publikováno v:
Journal of Electroanalytical Chemistry. 660:224-229
Kinetics of hydrogen evolution reaction on the electrodeposited gold electrode is studied. In semi-logarithmic coordinates, polarization curves consist of two linear segments with Tafel slopes 0.06 V at lower overpotentials and 0.12 V at the higher o
Autor:
L. A. Khanova
Publikováno v:
Russian Journal of Electrochemistry. 45:1206-1210
In order to develop the electrodes convenient for investigating the high-rate redox reactions not distorted by a reagent adsorption, the modification of amalgamated Pt electrodes with a monolayer of irreversibly adsorbed porphyrin is studied. A speci
Publikováno v:
Russian Journal of Electrochemistry. 43:1350-1357
The electrochemical reactions of ruthenium(II) bis(triethylenediamine)tetra-tret-butyl-phthalocyaninate in dimethylformamide are studied. Two reversible redox reactions on the platinum amalgam electrode are revealed at the potentials of −0.73 and
Autor:
Yu. E. Evstefeeva, L. A. Khanova
Publikováno v:
Russian Journal of Electrochemistry. 42:1079-1084
Cathodic reduction of oxygen and hydrogen peroxide on amalgamated platinum electrodes, which are coated with monolayers of long-chain aliphatic compounds cetyl alcohol (CA) and stearic acid (SA), is retarded as compared with the same reactions on cle
Publikováno v:
Chemical Physics. 326:33-42
The redox potentials of the cobalticenium–cobaltocene couple have been determined voltammetrically in several aqueous–organic mixed solvents. The cosolvents studied were dimethylformamide, acetone, 1,4-dioxane (all three disrupting the 3D network
Autor:
Yu. E. Evstefeeva, L. A. Khanova
Publikováno v:
Russian Journal of Electrochemistry. 42:609-614
The reduction of hydrogen peroxide and, for comparison, oxygen on an amalgamated platinum electrode covered with a monolayer of stearic acid is studied by methods of polarization curves and impedance spectroscopy. In contrast with the oxygen reductio
Autor:
L. A. Khanova, Yu. E. Evstefeeva
Publikováno v:
Russian Journal of Electrochemistry. 41:778-782
Electrochemical impedance spectra are obtained in a wide potential range for electrodes covered by monolayers of cetyl alcohol and stearic acid. The conditions for the determination of true values of the monolayer’s capacitance and ohmic resistance
Publikováno v:
Russian Journal of Electrochemistry. 41:287-293
An analysis of techniques used for the determination of the free energy of the transport of an individual ion out of water into an aprotic solvent shows that the most reliable technique at present seems to be a method based on the determination of po
Publikováno v:
Russian Journal of Electrochemistry. 40:794-801
Redox potentials of the first and second steps of the cobalticenium reduction in a low-permittivity solvent (glyme; dielectric constant 7.2) are determined. A spectral method is used to investigate the effect the supporting-salt concentration exerts
Publikováno v:
Russian Journal of Electrochemistry. 39:66-73
Properties of monolayers of cetyl, stearyl, and eicosyl alcohols and stearic and behenic acids and their mixtures are studied, along with the kinetics of a redox reaction of hemin adsorbed on these monolayers. Three-dimensional computer models of cor