Zobrazeno 1 - 10
of 28
pro vyhledávání: '"L F Kozin"'
Publikováno v:
Protection of Metals and Physical Chemistry of Surfaces. 50:178-182
A technique of covering stainless steel electrodes with a thin galvanic nickel coating containing vanadium-pentoxide particles as inclusions is developed, and regularities of the cathodic evolution of hydrogen on the modified electrodes in 30% KOH so
Publikováno v:
Russian Journal of Applied Chemistry. 86:1333-1339
To improve the purity of cobalt produced by electrochemical refining, the optimal electrolyte composition and electrolysis mode were determined and a method for diminishing the electrochemical activity of impurity metals in anodic dissolution of the
Publikováno v:
Protection of Metals and Physical Chemistry of Surfaces. 46:528-533
Regularities of the cathodic evolution of hydrogen from 30% KOH solution on titanium and cobalt electrodes, the surfaces of which are modified with an electrolytic Mo-Co alloy containing 85–88% molybdenum, are studied. Hydrogen evolution overpotent
Autor:
L. F. Kozin, A. V. Gaidin
Publikováno v:
Russian Journal of Applied Chemistry. 82:406-415
Mechanism of gallium discharge and ionization on a liquid gallium electrode in a fluoride-alkaline electrolyte was studied. The exchange currents, transfer coefficients in the cathodic and anodic processes, and the activation energy of the electrode
Publikováno v:
Protection of Metals and Physical Chemistry of Surfaces. 45:25-30
Kinetic characteristics of electrochemical hydrogen evolution at manganese rotating disc electrode in ammonium-bromide-perchloric solution at 18, 40, and 60°C are determined (the overvoltage, Tafel slopes, exchange currents, and activation energy).
Publikováno v:
Protection of Metals. 43:537-541
Analysis of the cathodic and anodic polarization curves recorded on manganese in a 2.0 M MnCl2 + 2.0 M NH4Cl solution (pH 5.5 ± 0.1 and t = 18 to 60°C) reveals the multistage character of the discharge-ionization of manganese in such a solution inv
Publikováno v:
Russian Journal of Applied Chemistry. 80:730-733
Halide-ammonium electrolytes were developed for electrochemical production of high-purity manganese.
Publikováno v:
Russian Journal of Physical Chemistry. 80:1392-1402
The kinetics and mechanism of dissolution of gold in solutions of thiocarbamide (T) in the presence of Fe2(SO4)3 as an oxidizer were studied. The dependences of the rate of dissolution of gold on the concentration ratio between iron(III) and T and pH
Autor:
L. F. Kozin, B. I. Danil’tsev
Publikováno v:
Protection of Metals. 41:341-348
The effect of thiocyanate on the corrosion dissolution rate of silver in thiosemicarbazide (TSC) ammonium-chloride-bromide solutions was studied by using gravimetry and rotating disc electrode technique. The corrosion dissolution of silver was shown
Publikováno v:
Protection of Metals. 41:349-353
The mechanism of the cobalt anodic ionization in 2.5 M CoCl2 solution (pH 3.5 ± 0.2, t = 15–60°C) is studied with the use of rotating disk electrode and rotating ring-disk electrode methods. The experimental data showed that the ionization procee