Zobrazeno 1 - 10
of 35
pro vyhledávání: '"L Bert Klumperman"'
Publikováno v:
Polymer Chemistry, 4(18), 4955-4965. Royal Society of Chemistry
New thermoset systems based on disulfide bonds were synthesized with self-healing capabilities. The self-healing mechanism is not related to disulfide–disulfide exchange reactions, but to thiol–disulfide exchange reactions that are pH-dependent.
Publikováno v:
Macromolecular Rapid Communications. 31:1846-1862
The mechanistic interpretation of kinetic anomalies in reversible addition-fragmentation chain transfer (RAFT)-mediated polymerization is critically reviewed. The main conclusion of this exercise is that available data do not allow model discriminati
Publikováno v:
Journal of Polymer Science, Part A: Polymer Chemistry, 48(22), 5215-5230. Wiley
This study describes the synthesis of well-defined nanocapsules via the miniemulsion technique. Pentaerythritol tetrakis(3-mercaptopropionate) (TetraThiol) or 1,6-hexanediol di(endo, exo-norborn-2-ene-5-carboxylate) (DiNorbornene) is used as the oil
Publikováno v:
Composites Science and Technology, 69(5), 656-662. Elsevier
New methods for the incorporation of single-walled carbon nanotubes (SWCNTs) into styrene-divinylbenzene-based high internal phase emulsions (HIPEs) are addressed with specific attention to minimizing the SWCNT loading while maintaining a high level
Autor:
L Bert Klumperman, Pap Patricia Geelen
Publikováno v:
Macromolecules, 40(11), 3914-3920. American Chemical Society
Rate retardation in reversible addition-fragmentation chain transfer (RAFT)-mediated polymerizations is the topic of an ongoing debate. One of the main explanations for this rate retardation is termination of the intermediate radical. The use of a RA
Autor:
Xulin Jiang, Jcm José Brokken-Zijp, Vgr Vincent Lima, Peter J. Schoenmakers, Rob van der Linde, L Bert Klumperman
Publikováno v:
Polym.Sci.: Part A: Polym.Chem., 43(5), 959-973. John Wiley and Sons Inc.
Journal of Polymer Science, Part A: Polymer Chemistry, 43(5), 959-973. Wiley
Journal of Polymer Science, Part A: Polymer Chemistry, 43(5), 959-973. Wiley
The reversible addition–fragmentation chain transfer (RAFT) polymerization technique has been employed to synthesize linear α,ω -telechelic polymers with either hydroxyl or carboxyl end groups. Methyl methacrylate, butyl methacrylate, and butyl a
Publikováno v:
Macromolecular Chemistry and Physics, 205(16), 2161-2168. Wiley-VCH Verlag
A combination of reversible addition-fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) techniques were applied for the synthesis of novel polymer brushes by using the grafting from approach or a combin
Autor:
L Bert Klumperman, J. B. McLeary, Jean M. McKenzie, Ronald D. Sanderson, Matthew P. Tonge, FM Calitz
Publikováno v:
Macromolecules, 37(7), 2383-2394. American Chemical Society
In situ 1H NMR (NMR) spectroscopy has been used to directly investigate the processes that occur during the early stages (typically the first few monomer addn. steps) of an AIBN-initiated reversible addn.-fragmentation chain transfer polymn. of styre
Autor:
Matthew P. Tonge, Ronald D. Sanderson, Jean M. McKenzie, L Bert Klumperman, FM Calitz, J. B. McLeary
Publikováno v:
Macromolecules, 36(26), 9687-9690. American Chemical Society
The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conver
Publikováno v:
Macromolecules, 35(12), 4785-4790. American Chemical Society
A new kinetic equation for copper-mediated ATRP is introduced based on the exptl. observation that the deactivator concn. ([CuII]) remains const. throughout the polymn. This const. deactivator concn. can originate from the use of a heterogeneous tran