Zobrazeno 1 - 10
of 45
pro vyhledávání: '"László Szepes"'
Publikováno v:
Organometallics. 31:3620-3627
Threshold photoelectron photoion coincidence spectroscopy was used to study a series of cobalt–organic complexes with phosphine and phosphine analogue ligands: PMe3Co(CO)2NO, PEt3Co(CO)2NO, AsMe3Co(CO)2NO, and SbMe3Co(CO)2NO. The two lowest energy
Publikováno v:
Organometallics. 29:724-731
The electronic structure of organometallic complexes with the phosphine analogue ligands trimethylarsine and trimethylstibine was studied. Four new complexes, CpMn(CO)2AsMe3, CpMn(CO)2SbMe3, Co(CO)...
Publikováno v:
Journal of Organometallic Chemistry. 694:2923-2926
A new series of isonitrile-substituted cobalt tricarbonyl nitrosyl (Co(CO) 2 (NO)CNR, R = Me, Et, n Pr, i Pr, n Bu, n Pe, CH 2 Si(CH 3 ) 3 ) has been synthesized, and their He I ultraviolet photoelectron spectra are reported. The assignment of the ba
Autor:
Ernő Kuzmann, László Szepes, Roland Szalay, Zoltán Homonnay, Imre Pápai, Peter de Châtel, Zoltán Klencsár, Attila Vértes
Publikováno v:
Structural Chemistry. 20:453-460
The compound Fe[C(SiMe3)3]2 has been prepared and investigated by the means of powder X-ray diffractometry and 57Fe Mossbauer spectroscopy. The compound’s unique geometry, in which iron is linearly coordinated by the two C(SiMe3)3 ligands, results
Autor:
Ernő Kuzmann, Roland Szalay, László Szepes, Attila Vértes, Peter de Châtel, Zoltán Homonnay, Imre Pápai
Publikováno v:
Hyperfine Interactions. 185:185-189
Fe[C(SiMe3)3]2 compound, in which iron is coordinated by two carbons, was prepared using the reaction of FeCl2 with (Me3Si)3CLi, and investigated by XRD, 57Fe Mossbauer spectroscopy and DFT calculations. 157.5 T hyperfine magnetic field was found at
Autor:
László Szepes, Alberto Modelli
Publikováno v:
Chemical Physics. 286:165-172
The energies of vertical electron attachment to the permethylated group 14 dimers (CH3)3M–M′(CH3)3, with M,M′=Si, Ge, Sn, were measured by means of electron transmission spectroscopy. The tin derivatives show the best electron-acceptor properti
Publikováno v:
Organometallics. 21:2751-2757
The HeI photoelectron spectra of trimethylaluminum, triethylaluminum, dimethylaluminum, and diethylaluminum hydrides were recorded as a function of temperature. From the spectra observed at different temperatures the spectra of the pure monomers and
Publikováno v:
Journal of Organometallic Chemistry. 695:1609-1611
He I photoelectron spectra of bis-(trimethylsilyl)-mercury and its gas phase thermolysis product, Me 3 Si radical, are reported. The first vertical ionization energies were determined to be 7.37 and 7.32 eV, respectively, and compared to calculated v
Publikováno v:
Chem. Educ. Res. Pract.. 1:179-182
An advanced inorganic and organometallic laboratory programme has been worked out for junior students. The laboratory exercises were selected to provide an introduction for the students to the different techniques and compound classes of inorganic an