Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Kyohei Otsuka"'
Autor:
Soichiro Kyushin, Yoshikuni Kurosaki, Kyohei Otsuka, Haruna Imai, Shintaro Ishida, Toru Kyomen, Minoru Hanaya, Hideyuki Matsumoto
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Examples of π single bonds in diradicals are rare, as they are typically unstable. Here, the authors describe a room temperature-stable closed-shell bicyclic tetrasilane that features a Si-Si π single bond between two of the non-adjacent Si centers
Externí odkaz:
https://doaj.org/article/ac2c92f277e640fe9f5604a632dc33cb
Autor:
Soichiro Kyushin, Yoshikuni Kurosaki, Kyohei Otsuka, Haruna Imai, Shintaro Ishida, Toru Kyomen, Minoru Hanaya, Hideyuki Matsumoto
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-2 (2021)
Externí odkaz:
https://doaj.org/article/8907a997a45c40e8a8dcf8b773b29d51
Publikováno v:
Acta Crystallographica Section E, Vol 69, Iss 3, Pp o341-o341 (2013)
The title compound, C28H52Si8, was synthesized by condensation of two molecules of 1,2,3,4-tetrakis(chlorodimethylsilyl)benzene with lithium. The 3,4-disila-1,2-benzocyclobutene rings in the centrosymmetric molecule are bridged by 1,1,2,2-tetramethyl
Externí odkaz:
https://doaj.org/article/c360e5f3138340899f04ae1c23019434
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 2, Pp o424-o424 (2012)
The title compound, C40H56Cl2Si4, was synthesized by the coupling of 1,1-di-tert-butyl-1,2-dichloro-2,2-diphenyldisilane with lithium. The asymmetric unit contains one half-molecule, which is completed by an inversion centre. In the molecule, the tet
Externí odkaz:
https://doaj.org/article/e2af15507ac34680b2687874595d6834
Autor:
Shintaro Ishida, Minoru Hanaya, Haruna Imai, Toru Kyomen, Kyohei Otsuka, Yoshikuni Kurosaki, Soichiro Kyushin, Hideyuki Matsumoto
Publikováno v:
Nature Communications
Nature Communications, Vol 12, Iss 1, Pp 1-2 (2021)
Nature Communications, Vol 12, Iss 1, Pp 1-2 (2021)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::476933e72996cd1ec0837bcfa2dc921b
https://doi.org/10.1038/s41467-021-24239-w
https://doi.org/10.1038/s41467-021-24239-w
Autor:
Haruna Imai, Minoru Hanaya, Shintaro Ishida, Kyohei Otsuka, Toru Kyomen, Soichiro Kyushin, Yoshikuni Kurosaki, Hideyuki Matsumoto
Publikováno v:
Nature Communications
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
A carbon–carbon double bond consists of a σ bond and a π bond. Recently, the concept of a π single bond, where a π bond is not accompanied by a σ bond, has been proposed in diradicals containing carbon and heteroatom radical centers. Here we r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e750a1f29e5b62d4ad5b4f676cfe3cc9
http://europepmc.org/articles/PMC7419521
http://europepmc.org/articles/PMC7419521
Publikováno v:
Intelligent Vehicles Symposium
The mechanism behind collisions between vehicles and pedestrians must be thoroughly studied in order to prevent future traffic accidents. In particular, preventing collisions where pedestrian steps out onto the road from behind an obstruction such as
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e8cb74161a25a843c25e746a00e2a43d
https://doi.org/10.1109/ivs.2017.7995728
https://doi.org/10.1109/ivs.2017.7995728
Publikováno v:
Chemistry - A European Journal. 20:9263-9266
The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a46413f878e68277da6fb64cfb2490fe
https://doi.org/10.1002/chem.201403375
https://doi.org/10.1002/chem.201403375
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 72:1290-1297
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::41ec17f684f1868a5b4e6c6a9129eeab
https://doi.org/10.5059/yukigoseikyokaishi.72.1290
https://doi.org/10.5059/yukigoseikyokaishi.72.1290
Publikováno v:
Journal of the American Chemical Society. 135:16340-16343
Cyclopentasilane-fused hexasilabenzvalene 1 was synthesized by the reduction of tetrachlorocyclopentasilane 6 in 19% yield as a green powder. The molecular structure and properties of 1 were studied by spectroscopic and X-ray crystallographic analyse
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::260aacbd8c24f1deaa4151fb76c2f218
https://doi.org/10.1021/ja409074m
https://doi.org/10.1021/ja409074m