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Publikováno v:
Tetrahedron Letters. 52:6988-6990
An enantioselective synthesis of methyl (+)-7-methoxyanodendroate was achieved utilising a Claisen rearrangement, a Grubbs cross-metathesis, and a Shi epoxidation-cyclisation sequence, confirming the absolute configuration assigned to the natural pro
Publikováno v:
ChemInform. 42
The Pd-catalyzed arylation of methyl derivative (I) gives the double-Heck product (III), whereas reaction with benzenesulfinic acid (IV) results in rearrangement to produce chroman structures (V) and (XI).