Zobrazeno 1 - 10
of 125
pro vyhledávání: '"Kurt Schank"'
Publikováno v:
Helvetica Chimica Acta. 90:1606-1649
Thioreductones and Derivatives. Replacement of one or two (principally also three) O-atoms in aci-reductones by sulfur leads to the corresponding thioreductones. In the present paper, different methods of their synthesis are discussed. Substitution o
Publikováno v:
Helvetica Chimica Acta. 88:3174-3199
Aminoreductones – Investigations on Species Containing the Carbon Arrangement of Dimedone and Secondary Amines as Building Blocks The ozonation of 3-(sec-amino)-5,5-dimethylcyclohex-2-en-1-ones 4 was compared with the corresponding acyloxylations b
Publikováno v:
Helvetica Chimica Acta. 87:2025-2049
Ozonolysis of Enol Ethers. Part 8. Ozonation of (1-Methoxy-2-methylprop-1-enyl)-1,1′-biphenyl in Comparison with Related Oxygenations The results of conversions of 4-(1-methoxy-2-methylprop-1-enyl)-1,1′-biphenyl (19) with ozone and with dimethyld
Autor:
Kurt Schank
Publikováno v:
Helvetica Chimica Acta. 87:2074-2084
The Mechanism of Alkene Ozonolysis – a Critical Examination. Alkene ozonolyses have been carried out in experimental organic chemistry for more than a century, and a lucid description of the underlying reaction mechanism has been developped and int
Publikováno v:
Helvetica Chimica Acta. 87:869-924
Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds (‘1,2,3-Triones’). Part 3. Polar and Redox Reactions of 1,2,3-Triones with Enamines of Different Types – News on Oxonol Dyes, Radicals, and Biradicals The central CO groups of cyclic 1,2,3-
Publikováno v:
Helvetica Chimica Acta. 84:2071-2088
Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds (`1,2,3-Triones'). Part 1. Reaction of Diazomethane and Its Derivatives with 5,5-Dimethylcyclohexane-1,2,3-trione (=`Oxo-dimedone') and Related Cyclohexane-1,2,3-triones Interactions of diazometh
Publikováno v:
Helvetica Chimica Acta. 84:1943-1951
Allenyl methyl ether (1) and (diphenylmethylene)cyclopropane (5) were ozonized with an ozone/oxygen mixture. Formation of the observed products cannot be satisfactorily rationalized via the familiar modified Criegee mechanism. However, a single-elect
Publikováno v:
Helvetica Chimica Acta. 83:3312-3332
Surprising Results during the Re-investigation of the Formation and Decomposition of Triptene Ozonide. Revision of the ozonolysis of triptene (=2,3,3-trimethylbut-1-ene; 1) revealed that molecular oxygen of an applied ozone/oxygen gas mixture partici
Publikováno v:
Helvetica Chimica Acta. 83:1611-1624
Alkynes of sufficiently high nucleophilicity react with electrophilic O3 under conversion of the alkyne function to a vicinal dicarbonyl function. Contrary to earlier investigations with alkylated or arylated acetylene, products of complete C−C cle
Autor:
Susanne Pistorius, Jörg Eder, Kurt Schank, Horst P. Beck, Christiane Wagner, Michael Buschlinger, Thomas Heisel
Publikováno v:
Helvetica Chimica Acta. 83:801-826
Ozonolyses of 1,1,2,2-tetraphenylethene (TPE, 1) have been described many times in the literature, but the reports are contradictory. This reaction is particularly important for understanding the mechanism of alkene ozonolysis, in view of possible st