Thermogalvanic cells demonstrate inherent physiochemical limitations in redox-active electrolytes at water-in-salt concentrations

Autor: Mark A. Buckingham, Kristine Laws, Huanxin Li, Yafei Kuang, Leigh Aldous

Publikováno v: Cell Reports Physical Science, Vol 2, Iss 8, Pp 100510- (2021)

Summary: The majority of usable energy generated by humanity is lost as waste heat, but thermogalvanic systems (or thermocells) can address this problem by converting low-grade waste heat directly into electricity using redox chemistry. The concentra

Externí odkaz: https://doaj.org/article/54354a610b454f948307734f10edc2a8

High Seebeck coefficient thermogalvanic cells via the solvent-sensitive charge additivity of cobalt 1,8-diaminosarcophagine

Autor: Kristine Laws, Mark A. Buckingham, Matthew Farleigh, Michelle Ma, Leigh Aldous

Publikováno v: Chemical Communications. 59:2323-2326

This study demonstrates the charge additivity of core valence metal ions with fixed ionic pendant groups can significantly boost the thermoelectrochemical valorisation of waste heat into electricity, but is solvent-specific.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::249d744fc50d64b6e6afbb260b7b6687
https://doi.org/10.1039/d2cc05413b

Investigating the effect of steric hindrance within CdS single-source precursors on the material properties of AACVD and spin coat-deposited CdS thin films

Autor: Mark A. Buckingham, Kane Norton, Paul D. McNaughter, George Whitehead, Inigo Vitorica-Yrezabal, Firoz Alam, Kristine Laws, David J. Lewis

Publikováno v: Buckingham, M, Norton, K, Mcnaughter, P, Whitehead, G, Vitorica-Yrezabal, I, Alam, F, Laws, K & Lewis, D 2022, ' Investigating the effect of steric hindrance within CdS single-source precursors on the material properties of AACVD and spin coat-deposited CdS thin films ', Inorganic Chemistry, vol. 61, no. 21, pp. 8206–8216 . https://doi.org/10.1021/acs.inorgchem.2c00616

Cadmium sulfide (CdS) is an important semiconductor for electronic and photovoltaic applications, particularly when utilised as a thin film for window layers in CdTe solar cells. Deposition of thin film CdS through the decomposition of single source

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c9dd30a3df684c8a05159cf577cd20c
https://doi.org/10.1021/acs.inorgchem.2c00616

The Next Generation of Anticancer Metallopharmaceuticals: Cancer Stem Cell-Active Inorganics

Autor: Kogularamanan Suntharalingam, Kristine Laws

Publikováno v: ChemBioChem. 19:2246-2253

Cancer stem cells (CSCs) are heavily linked to fatal incidences of cancer relapse and metastasis. Conventional cancer therapies such as surgery, chemotherapy and radiation are largely futile against CSCs. Therefore, highly original approaches are nee

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ed210f0c5014bc114ae272827e6f7a50
https://doi.org/10.1002/cbic.201800358

A Copper(II) Phenanthroline Metallopeptide That Targets and Disrupts Mitochondrial Function in Breast Cancer Stem Cells

Autor: Arvin Eskandari, Chunxin Lu, Kogularamanan Suntharalingam, Kristine Laws, Nicola O’Reilly, Ganka Bineva-Todd

Publikováno v: Angewandte Chemie. 130:293-297

The breast cancer stem cell (CSC) and bulk breast cancer cell potency of a series of metallopeptides containing dichloro(1,10-phenanthroline)copper(II) and various organelle-targeting peptide sequences is reported. The mitochondria-targeting metallop

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35b8a84c295bc4e7870ddc7e48dc69c2
https://doi.org/10.1002/ange.201710910