Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Kristin Williams Fiori"'
Publikováno v:
Nature chemistry
While Nature excels at performing selective modifications of complex polyfunctional molecules through the use of tailoring enzymes, synthetic chemistry has lagged behind in this regard. In prior work, we have applied a biomimetic approach to this pro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a42ef585cb82e4b59604dec1282502a2
https://doi.org/10.1038/nchem.410
https://doi.org/10.1038/nchem.410
Publikováno v:
Tetrahedron. 65:3042-3051
A detailed mechanistic investigation of the intramolecular dirhodium tetracarboxylate-catalyzed sulfamate ester C–H amination reaction is presented. These studies provide support for the formation of a sulfamate-derived iminoiodinane, which reacts
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::071f9c8c6871e6a9085896b211cd1b3b
https://doi.org/10.1016/j.tet.2008.11.073
https://doi.org/10.1016/j.tet.2008.11.073
Autor:
J. Du Bois, Kristin Williams Fiori
Publikováno v:
Journal of the American Chemical Society. 129:562-568
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::77caeb09163e96c1e7be8454698408cc
https://doi.org/10.1021/ja0650450
https://doi.org/10.1021/ja0650450
Publikováno v:
Angewandte Chemie. 116:4449-4452
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2095ff6015bda820834bb8fc06bd45bb
https://doi.org/10.1002/ange.200460791
https://doi.org/10.1002/ange.200460791
Publikováno v:
Journal of the American Chemical Society. 126(47)
Analysis of the mechanism for Rh-mediated C−H amination has led to the development of a remarkably effective dinuclear Rh catalyst derived from 1,3-benzenedipropionic acid. This unique complex, Rh2(esp)2, is capable of promoting both intra- and int
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c3c8faccc8d06659dd262cff6f04cfd2
https://pubmed.ncbi.nlm.nih.gov/15563154
https://pubmed.ncbi.nlm.nih.gov/15563154
Publikováno v:
ChemInform. 34
Access to stereochemically complex, polyfunctionalized amine derivatives is made possible using novel oxathiazinane N,O-acetal starting materials. These heterocycles are prepared through intramolecular sulfamate ester C-H insertion with a Rh(2+)-carb
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f7627f9a702809467f48126ef3f364a6
https://doi.org/10.1002/chin.200323155
https://doi.org/10.1002/chin.200323155
Publikováno v:
Angewandte Chemie International Edition; Aug2004, Vol. 43 Issue 33, p4349-4352, 4p