Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Kristin Voiges"'
Autor:
Petra Mischnick, Kristin Voiges, Julia Cuers-Dammann, Inga Unterieser, Patrick Sudwischer, Anika Wubben, Payam Hashemi
Publikováno v:
Polysaccharides, Vol 2, Iss 4, Pp 843-865 (2021)
The complexity of the substituent distribution in polysaccharide derivatives is discussed and defined. The challenges regarding analytical characterization that results from various interrelated categories of distributions, including molecular weight
Externí odkaz:
https://doaj.org/article/ee35fc8d4a2c45be9c78732f873ba660
Publikováno v:
Cellulose. 24:627-639
The rate of acid-catalyzed hydrolysis of O-ethyl-O-methyl-cellulose (EMC) and O-methoxyethyl-O-methyl-cellulose (MEMC), respectively, has been studied. By a two-step depolymerization procedure and monitoring of all individual substitution patterns, r
Publikováno v:
Cellulose. 24:555-569
The kinetics of the hydrolysis of methyl cellulose (MC, DS 1.27 and 1.95) was studied by a two-step procedure, comprising partial hydrolysis in 1 M TFA in water and water/acetone at 120 °C for various time periods, labeling of generated reducing end
Publikováno v:
Macromolecular Chemistry and Physics. 214:1363-1374
Hydroxyethylmethyl celluloses (MSHE 0.15–0.26, DSMe 1.49–1.82) and hydroxyethyl celluloses (MSHE 1.89–3.03) are analyzed with respect to their substituent distribution in the polymer chains. The cellulose ethers are peralkylated and partially h
Autor:
Christian Bork, Rudi F. Vogel, Markus J. Brandt, Heinrich Rübsam, Thomas Becker, Petra Mischnick, Christine Rühmkorf, Kristin Voiges
Publikováno v:
European Food Research and Technology. 235:139-146
The effect of structurally different bacterial homoexopolysaccharides on gluten-free bread quality and their properties to act as hydrocolloids was investigated. Furthermore, exopolysaccharides (EPS) were analyzed structurally by asymmetrical flow fi
Publikováno v:
Cellulose. 19:993-1004
The alditol acetate method is a common procedure for sugar analysis, also applied to determine the substituent distribution in monomer units of polysaccharide ethers like methyl cellulose by gas liquid chromatography. Consisting of several preparatio
Publikováno v:
Rapid Communications in Mass Spectrometry. 25:2201-2208
Mass spectrometry is widely applied in carbohydrate analysis, but still quantitative evaluation of data is critical due to different ionization efficiencies of the constituents in a mixture. Different size and chemical structure of the analytes cause
Publikováno v:
European Polymer Journal. 46:1726-1735
Spruce sulphite cellulose (number average degree of polymerization 620) dissolved in an aqueous solution of 8% (w/w) LiOH*H2O and 12% (w/w) urea was methylated with dimethyl sulphate (DMS). By varying the reaction temperature between 22 and 50 °C, t
Publikováno v:
Biomacromolecules. 13(7)
Regioselective synthesis of cellulose esters is extremely difficult due to the small reactivity differences between cellulose hydroxyl groups, small differences in steric demand between acyl moieties of interest, and the difficulty of attaching and d
Publikováno v:
Analytical and bioanalytical chemistry. 395(6)
Dextrans from Leuconostoc ssp., alpha-1,6-linked glucans branched at O-3, were O-methylated in DMSO with lithium dimsyl and methyl iodide under various conditions. Methyl substituent distribution was comprehensively studied in the terminal, internal,