Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Koya Inomata"'
Autor:
Koya Inomata, Yuki Naganawa, Zhi An Wang, Kei Sakamoto, Kazuhiro Matsumoto, Kazuhiko Sato, Yumiko Nakajima
Publikováno v:
Communications Chemistry, Vol 4, Iss 1, Pp 1-9 (2021)
Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.
Externí odkaz:
https://doaj.org/article/248c7532ea7146be83c0519f270e6480
Publikováno v:
Organometallics. 42:846-858
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ac2c1fd9e6418b61bed68c4dd38b03a6
https://doi.org/10.1021/acs.organomet.3c00139
https://doi.org/10.1021/acs.organomet.3c00139
Autor:
Shigeru Shimada, Keiya Aoyagi, Kazuhiko Sato, Yu Ohmori, Yumiko Nakajima, Kazuhiro Matsumoto, Koya Inomata
Publikováno v:
Chemical Communications. 55:5859-5862
Hydrosilanes were synthesized by reduction of alkoxysilanes with BH3 in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easy-to-handle handled hydride source NaBH4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b2fbcb083724d1ab5a3b81c9bfb80cc9
https://doi.org/10.1039/c9cc01961h
https://doi.org/10.1039/c9cc01961h
Autor:
Kei Sakamoto, Kazuhiko Sato, Zhi An Wang, Yumiko Nakajima, Kazuhiro Matsumoto, Yuki Naganawa, Koya Inomata
Publikováno v:
Communications Chemistry, Vol 4, Iss 1, Pp 1-9 (2021)
The transition-metal-catalysed hydrosilylation reaction of alkenes is one of the most important catalytic reactions in the silicon industry. In this field, intensive studies have been thus far performed in the development of base-metal catalysts due
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::46ccd2ef7c9c26b461347bdfd54f5ece
https://doi.org/10.1038/s42004-021-00502-5
https://doi.org/10.1038/s42004-021-00502-5
Autor:
Keiya, Aoyagi, Yu, Ohmori, Koya, Inomata, Kazuhiro, Matsumoto, Shigeru, Shimada, Kazuhiko, Sato, Yumiko, Nakajima
Publikováno v:
Chemical communications (Cambridge, England). 55(42)
Hydrosilanes were synthesized by reduction of alkoxy silanes with BH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::893b2f71b99d9a19d08b55c7807fd6c3
https://pubmed.ncbi.nlm.nih.gov/31038143
https://pubmed.ncbi.nlm.nih.gov/31038143
Publikováno v:
Tetrahedron Letters. 61:151513
Hydrosilylation of alkenes is an important reaction for the production of organosilicon compounds such as industrially important silicones and silane coupling agents. To synthesize highly sophisticated organosilicon materials, it is of great importan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::285ca44c04cf86a73646338160dfe457
https://doi.org/10.1016/j.tetlet.2019.151513
https://doi.org/10.1016/j.tetlet.2019.151513
Publikováno v:
Journal of the American Chemical Society. 136:14341-14344
Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::72ffafbad9d124390e19ce6a0cc60282
https://doi.org/10.1021/ja506018f
https://doi.org/10.1021/ja506018f
Publikováno v:
Tetrahedron Letters. 60:151086
Reactions of allyl-functionalized poly(ethylene glycol) (PEG) derivatives with alkoxysilanes proceeded efficiently to furnish the corresponding hydrosilylated products in good to excellent yields using a ruthenium catalyst, [RuCl2(nbd)]n. A prelimina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::eb9dbb3e5e308378d56e8b4f5fd6b13e
https://doi.org/10.1016/j.tetlet.2019.151086
https://doi.org/10.1016/j.tetlet.2019.151086
Publikováno v:
Journal of the American Chemical Society. 137:11935-11937
A cationic germylene containing tungsten and N-heterocyclic carbene units reacted with H2 in fluorobenzene at 60 °C, resulting in its insertion into the H-H bond. It also activated the Si-H bond of ethyldimethylsilane and the B-H bond of pinacolbora
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3609016151fe1e8cdb4107f6519c5317
https://doi.org/10.1021/jacs.5b08169
https://doi.org/10.1021/jacs.5b08169