Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Kou-Sen Cao"'
Publikováno v:
Synthesis. 49:3670-3675
A first example of boronic acid catalyzed intermolecular aza-Piancatelli rearrangement to access a wide range of trans-4,5-disubstituted cyclopentenones is described. The catalytic system can also be extended to intramolecular aza-Piancatelli rearran
Publikováno v:
Chemical Communications. 53:3737-3740
The first highly enantioselective catalytic protocol for selective manipulation of tetrol benzylidene acetals through chiral phosphoric acid mediated oxidative desymmetrization is reported. This efficient approach provides a general access to vicinal
Autor:
Wen-Hua Zheng, Kou-Sen Cao
Publikováno v:
Tetrahedron: Asymmetry. 26:1150-1155
The first non-enzymatic desymmetrization of prochiral allenic diols via cooperative binary catalysis of Pd(OAc) 2 and ( R )-STRIP has been reported. This method allows easy access to a series of optically active disubstituted dihydrofurans through pa
Publikováno v:
Organic & Biomolecular Chemistry. 13:6449-6452
The first example of arylboronic acid catalyzed [4 + 3] cycloaddition reaction is reported. 3,5-Bis-(trifluoromethyl) phenylboronic acid is shown to be the best catalyst in this reaction. The method has also enabled the preparation of cyclohepta[b]be
Autor:
Yong Liang, Kendall N. Houk, Shan-Shui Meng, Xing-Bang Lin, Kou-Sen Cao, Lufeng Zou, Wen-Hua Zheng, Hui Yang
Publikováno v:
Journal of the American Chemical Society. 136:12249-12252
A highly enantioselective catalytic protocol for the desymmetrization of a wide variety of 2-substituted and 2,2-disubstituted 1,3-diols is reported. This reaction proceeds through the formation of an "ortho ester" intermediate via oxidation of 1,3-d
Autor:
Wen-Hua Zheng, Kou-Sen Cao
Publikováno v:
ChemInform. 47
The first non-enzymatic desymmetrization of prochiral allenic diols via cooperative binary catalysis of Pd(OAc) 2 and ( R )-STRIP has been reported. This method allows easy access to a series of optically active disubstituted dihydrofurans through pa
Publikováno v:
Inorganica Chimica Acta. 378:224-230
Six novel chiral double salts (1–6) composed of d -(+)-camphoric diammonium (LH2) and transition-metal sulfates, formulated as {[M(SO4)2(H2O)4](LH2)}·2H2O [M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II)], have been prepared and fully charac
Publikováno v:
Synthesis; 2017, Vol. 49 Issue 16, p3670-3675, 6p
Publikováno v:
ChemInform. 46
3,5-Bis(trifluoromethyl)benzeneboronic acid proves to be an efficient catalyst for the cycloaddition of allylic cations with various dienes under mild reaction conditions.
Autor:
Kendall N. Houk, Wen-Hua Zheng, Xing-Bang Lin, Kou-Sen Cao, Shan-Shui Meng, Lufeng Zou, Yong Liang, Hui Yang
Publikováno v:
ChemInform. 46
This highly enantioselective reaction proceeds through formation of an “ortho ester” intermediate via oxidation of the 1,3-diol benzylidene acetal by dimethyldioxirane and a subsequent proton transfer catalyzed by chiral phosphoric acids (CPA).