Tuning Molecular Electron Affinities against Atomic Electronegativities by Spatial Expansion of a π-System.

Autor: Chulanova EA; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation.; Current address: Institute for Applied Physics, University of Tübingen, 72076, Tübingen, Germany., Radiush EA; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Semenov NA; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Hupf E; Institute for Inorganic Chemistry and Crystallography, University of Bremen, 28359, Bremen, Germany., Irtegova IG; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Kosenkova YS; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Bagryanskaya IY; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Shundrin LA; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation., Beckmann J; Institute for Inorganic Chemistry and Crystallography, University of Bremen, 28359, Bremen, Germany., Zibarev AV; Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation.

Publikováno v: Chemphyschem : a European journal of chemical physics and physical chemistry [Chemphyschem] 2023 May 02; Vol. 24 (9), pp. e202200876. Date of Electronic Publication: 2023 Feb 20.