Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Konrad Kepski"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 20, Iss 1, Pp 2455-2460 (2024)
A change in mechanism was observed in the hypervalent iodine-mediated cyclization of N-alkenylamides when the carbon chain between the alkene and the amide increased from two to three atoms. In the latter case, cyclization at the amide nitrogen to fo
Externí odkaz:
https://doaj.org/article/ca0ec8c7cff44a1587db6df817b92310
Autor:
Konrad Kepski, Wesley James Moran
Publikováno v:
Organics, Vol 3, Iss 3, Pp 275-280 (2022)
Diaryliodonium salts are useful arylating reagents that have been exploited widely. In this Communication, we demonstrate that heating diphenyliodonium triflate in the solvent DMSO leads to an unexpected arylation reaction. It is postulated that aryl
Externí odkaz:
https://doaj.org/article/16d4d1030bc64f4898d926064dece5e0
Publikováno v:
Organic Letters. 21:6936-6939
A convenient, highly regioselective synthesis of five-membered cyclic vinyl(aryl)iodonium salts directly from β-iodostyrenes is presented. An X-ray crystal structure confirms the identity of these heterocycles. These λ3-iodanes can be converted rap