Zobrazeno 1 - 10
of 150
pro vyhledávání: '"Konrad G. Weil"'
Autor:
Konrad G. Weil, Karl Doblhofer
Publikováno v:
Methods in Physical Chemistry
Autor:
Konrad G. Weil, Georg Flätgen, Karl Doblhofer, Sarah L. Horswell, Bruno Pettinger, Sabine Wasle
Publikováno v:
Surface Science. 603:1900-1903
Recent electrochemical studies of the cathodic reduction of hydrogen peroxide (H 2 O 2 ) on silver electrodes in acidic electrolyte (HClO 4 ) revealed a novel autocatalytic reaction path. Adsorbed hydroxyl groups, OH ad , were proposed to act as the
Publikováno v:
ECS Transactions. 2:293-302
The role of the ammonium ion during iron deposition in a ferrous sulfate bath was investigated. When cathodic polarizations were performed in a solution of 0.02 M FeSO4 at pH 3, quartz crystal microbalance measurements showed that the presence of amm
Publikováno v:
The Journal of Physical Chemistry B. 108:14298-14304
Electrochemical microprobes for monitoring of the electrochemical conditions inside recesses are needed to better understand how localized corrosion and other charge-transfer processes occur in confined spaces. The electrode potential distribution ca
Publikováno v:
Electrochimica Acta. 48:3565-3572
This paper demonstrates the use of the new Iyer/Pickering/Zamanzadeh/Al-Faqeer (IPZA) analysis to determine the effect of the iodide surface coverage (θI−) on the hydrogen surface coverage (θH) and the rate constants of the hydrogen evolution rea
Autor:
Konrad G. Weil, Gerhard Ertl, Gisela Weinberg, David Mendez Soares, Sabine Wasle, Karl Doblhofer
Publikováno v:
Scopus-Elsevier
The cathodic reduction of copper(II) in an electrolyte comparable to technical conditions (2.2M H2SO4 + 0.3M CuSO4) is markedly affected by the presence of small concentrations of halide ions. Chloride ions accelerate the reaction, while it is slowed
Publikováno v:
Journal of Electroanalytical Chemistry. 532:353-358
The cathodic reduction of copper(II) is studied in the absence and in the presence of chloride ions (1×10−3≤cCl≤8×10−3 M) in an electrolyte that is comparable to galvanic copper baths (2.2 M H2SO4+0.3 M CuSO4). Experiments conducted with th
Publikováno v:
Electrochimica Acta. 46:3835-3840
A 70% Sn–30% Zn layer is deposited from a neutral non-cyanide bath. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) show that it is composed of Sn and Zn phases. By use of an electrochemical quartz crystal microbal
Publikováno v:
Electrochimica Acta. 45:3623-3628
Many electrochemical processes contain more than one charge transfer step. If one of these steps leads to a mass change of the working electrode one can use the electrochemical quartz crystal microbalance (EQCM) in situ to determine the rate of this
Publikováno v:
Physical Chemistry Chemical Physics. 2:5691-5697
Recently, it was shown that the reduction of hydrogen peroxide on silver in perchloric acid proceeds in two parallel paths. The normal reduction is observed at an overpotential of − 1.5 V whereas a second reduction reaction occurs at a significantl